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- W4362640347 abstract "We discuss layout and performance of a high-resolution Stimulated Raman Loss spectrometer that has been newly developed for accurate studies of spectral lineshapes and line centre frequencies of hydrogen isotopologues and in general of Raman active transitions. Thanks to the frequency comb calibration of the detuning between pump and Stokes lasers and to an active alignment of the two beams, the frequency accuracy is at a level of 50 kHz. Over the vertical axis the spectrometer benefits from shot-noise limited detection, signal enhancement via multipass cell, active flattening of the spectral baseline and measurement times of few seconds over spectral spans larger than 10 GHz. Under these conditions an efficient averaging of Raman spectra is possible over long measurement times with minimal distortion of spectral lineshapes. By changing the pump laser, transitions can be covered in a very broad frequency span, from 50 to 5000 cm−1, including both vibrational and rotational bands. The spectrometer has been developed for studies of fundamental and collisional physics of hydrogen isotopologues and has been recently applied to the metrology of the Q(1) 1–0 line of H2." @default.
- W4362640347 created "2023-04-07" @default.
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- W4362640347 date "2023-04-05" @default.
- W4362640347 modified "2023-09-25" @default.
- W4362640347 title "A stimulated Raman loss spectrometer for metrological studies of quadrupole lines of hydrogen isotopologues" @default.
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- W4362640347 doi "https://doi.org/10.1080/00268976.2023.2196353" @default.
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