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- W4362649167 abstract "By the deaminative coupling reaction of α-aminoesters and α-aminoacetonitriles with thiols, a new strategy for the synthesis of α-thioaryl esters and nitriles is described, representing an example of converting C(sp3)-N into C(sp3)-S bonds. The substrates form diazo compounds in situ in the presence of NaNO2, and then a transition-metal-free S-H bond insertion reaction occurs with thiophenol derivatives. The method is simple in operation and post-treatment and has good universality. The corresponding thioethers were obtained in moderate to good (up to 90%) yields under mild conditions." @default.
- W4362649167 created "2023-04-07" @default.
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- W4362649167 date "2023-01-01" @default.
- W4362649167 modified "2023-10-18" @default.
- W4362649167 title "Synthesis of α-Aryl Sulfides by Deaminative Coupling of α-Amino compounds with Thiophenols" @default.
- W4362649167 doi "https://doi.org/10.1039/d3ob00345k" @default.
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- W4362649167 hasPublicationYear "2023" @default.
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