FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4362663766> ?p ?o ?g. }

• W4362663766 endingPage "797" @default.
• W4362663766 startingPage "789" @default.
• W4362663766 abstract "Biological encapsulants, such as viral capsids and ferritin protein cages, use many identical subunits to tile the surface of a polyhedron. Inspired by these natural systems, synthetic chemists have prepared artificial nanocages with well-defined shapes and cavities. Rational control over the self-assembly of discrete, nanometre-scale, hollow coordination cages composed of simple components remains challenging as a result of the entropic costs associated with binding many subunits together, difficulties in the error-correction processes associated with assembly and increasing surface energy as their size grows. Here we demonstrate the construction of nanocages of increasing size derived from a single pentatopic pyrrole-based subcomponent. Reasoned shifts in the preferred coordination number of the metal ions used, along with the denticity and steric hindrance of the ligands, enabled the generation of progressively larger cages. These structural changes of the cages are reminiscent of the differences in the folding of proteins caused by minor variations in their amino acid sequences; understanding how they affect capsule structure and thus cavity size may help to elucidate the construction principles for larger and functional capsules, capable of binding and carrying large biomolecules as cargoes. Controlling the self-assembly of large coordination cages is challenging owing to entropic costs and difficulties in error correction. Now an array of large cages prepared by the rational design of alterations that allow for the tuning of the dihedral angle between pentagonal subunits is reported." @default.
• W4362663766 created "2023-04-07" @default.
• W4362663766 creator A5011847670 @default.
• W4362663766 creator A5016612577 @default.
• W4362663766 creator A5017470545 @default.
• W4362663766 creator A5023457299 @default.
• W4362663766 creator A5027807852 @default.
• W4362663766 creator A5034004588 @default.
• W4362663766 creator A5040398298 @default.
• W4362663766 creator A5044880136 @default.
• W4362663766 creator A5050079597 @default.
• W4362663766 creator A5083400295 @default.
• W4362663766 creator A5087018671 @default.
• W4362663766 date "2023-04-06" @default.
• W4362663766 modified "2023-10-18" @default.
• W4362663766 title "Systematic construction of progressively larger capsules from a fivefold linking pyrrole-based subcomponent" @default.
• W4362663766 cites W1608348054 @default.
• W4362663766 cites W1863777187 @default.
• W4362663766 cites W1965743698 @default.
• W4362663766 cites W1971775718 @default.
• W4362663766 cites W1976367433 @default.
• W4362663766 cites W1987790825 @default.
• W4362663766 cites W1987824072 @default.
• W4362663766 cites W1991860687 @default.
• W4362663766 cites W2003896402 @default.
• W4362663766 cites W2005790419 @default.
• W4362663766 cites W2006422372 @default.
• W4362663766 cites W2061215710 @default.
• W4362663766 cites W2078507839 @default.
• W4362663766 cites W2087155016 @default.
• W4362663766 cites W2091258356 @default.
• W4362663766 cites W2091383063 @default.
• W4362663766 cites W2131209038 @default.
• W4362663766 cites W2133044989 @default.
• W4362663766 cites W2145780146 @default.
• W4362663766 cites W2323224141 @default.
• W4362663766 cites W2471929598 @default.
• W4362663766 cites W2565825795 @default.
• W4362663766 cites W2597727278 @default.
• W4362663766 cites W2607042077 @default.
• W4362663766 cites W2775807539 @default.
• W4362663766 cites W2890523993 @default.
• W4362663766 cites W2895621985 @default.
• W4362663766 cites W2896383614 @default.
• W4362663766 cites W2904759704 @default.
• W4362663766 cites W2965859815 @default.
• W4362663766 cites W3015136968 @default.
• W4362663766 cites W3083339848 @default.
• W4362663766 cites W3097716688 @default.
• W4362663766 cites W3155614419 @default.
• W4362663766 cites W4206022889 @default.
• W4362663766 cites W4283374866 @default.
• W4362663766 doi "https://doi.org/10.1038/s44160-023-00276-9" @default.
• W4362663766 hasPublicationYear "2023" @default.
• W4362663766 type Work @default.
• W4362663766 citedByCount "5" @default.
• W4362663766 countsByYear W43626637662023 @default.
• W4362663766 crossrefType "journal-article" @default.
• W4362663766 hasAuthorship W4362663766A5011847670 @default.
• W4362663766 hasAuthorship W4362663766A5016612577 @default.
• W4362663766 hasAuthorship W4362663766A5017470545 @default.
• W4362663766 hasAuthorship W4362663766A5023457299 @default.
• W4362663766 hasAuthorship W4362663766A5027807852 @default.
• W4362663766 hasAuthorship W4362663766A5034004588 @default.
• W4362663766 hasAuthorship W4362663766A5040398298 @default.
• W4362663766 hasAuthorship W4362663766A5044880136 @default.
• W4362663766 hasAuthorship W4362663766A5050079597 @default.
• W4362663766 hasAuthorship W4362663766A5083400295 @default.
• W4362663766 hasAuthorship W4362663766A5087018671 @default.
• W4362663766 hasBestOaLocation W43626637662 @default.
• W4362663766 hasConcept C112887158 @default.
• W4362663766 hasConcept C128355301 @default.
• W4362663766 hasConcept C161790260 @default.
• W4362663766 hasConcept C171250308 @default.
• W4362663766 hasConcept C178790620 @default.
• W4362663766 hasConcept C185592680 @default.
• W4362663766 hasConcept C192562407 @default.
• W4362663766 hasConcept C201194858 @default.
• W4362663766 hasConcept C32909587 @default.
• W4362663766 hasConcept C53105671 @default.
• W4362663766 hasConcept C55493867 @default.
• W4362663766 hasConcept C71240020 @default.
• W4362663766 hasConcept C8010536 @default.
• W4362663766 hasConcept C89025888 @default.
• W4362663766 hasConceptScore W4362663766C112887158 @default.
• W4362663766 hasConceptScore W4362663766C128355301 @default.
• W4362663766 hasConceptScore W4362663766C161790260 @default.
• W4362663766 hasConceptScore W4362663766C171250308 @default.
• W4362663766 hasConceptScore W4362663766C178790620 @default.
• W4362663766 hasConceptScore W4362663766C185592680 @default.
• W4362663766 hasConceptScore W4362663766C192562407 @default.
• W4362663766 hasConceptScore W4362663766C201194858 @default.
• W4362663766 hasConceptScore W4362663766C32909587 @default.
• W4362663766 hasConceptScore W4362663766C53105671 @default.
• W4362663766 hasConceptScore W4362663766C55493867 @default.
• W4362663766 hasConceptScore W4362663766C71240020 @default.
• W4362663766 hasConceptScore W4362663766C8010536 @default.
• W4362663766 hasConceptScore W4362663766C89025888 @default.

• next