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• W4362705879 abstract "Abstract Herein we report a mild, efficient, and epimerization‐free method for the synthesis of peptide‐derived 2‐thiazolines and 5,6‐dihydro‐4 H ‐1,3‐thiazines based on a cyclodesulfhydration of N ‐thioacyl‐2‐mercaptoethylamine or N ‐thioacyl‐3‐mercaptopropylamine derivatives. The described reaction can be easily carried out in aqueous solutions at room temperature and it is triggered by change of the pH, leading to complex thiazoline or dihydrothiazine derivatives without epimerization in excellent to quantitative yields. The new method was applied in the total synthesis of the marine metabolite mollamide F, resulting in the revision of its stereochemistry." @default.
• W4362705879 created "2023-04-09" @default.
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• W4362705879 date "2023-05-11" @default.
• W4362705879 modified "2023-10-05" @default.
• W4362705879 title "Synthesis of Complex Thiazoline‐Containing Peptides by Cyclodesulfhydration of <i>N</i>‐Thioacyl‐2‐Mercaptoethylamine Derivatives" @default.
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• W4362705879 doi "https://doi.org/10.1002/anie.202301543" @default.
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