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- W4362732989 abstract "The electrochemical and spectroelectrochemical properties of the discotic mesogen 2,3,6,7,10,11-pentyloxytriphenylene (H5T) were studied with the use of cyclic voltammetry combined with UV-Vis and electron paramagnetic resonance (EPR) spectroscopy in solution. The UV-Vis absorption spectroscopy of H5T in dichloromethane showed its monomeric state in a concentration range up to 10−3 mol dm−3. The reversible process of the electrochemical formation of the radical cation was evidenced within the experimentally accessible potential window. The in situ UV-Vis spectroelectrochemical measurements further enabled identification of the product of the redox process and evaluation of the effect of aggregation in the concentration range of 5 × 10−3 mol dm−3. The results are discussed in the frame of solvent effects on the self-assembly propensity of solute molecules, in a wide range of concentrations. In particular, the crucial role of the solvent polarity is indicated, which contributes to the understanding of solution effects and pre-programming of supramolecular organic materials, in particular anisotropic disc-shaped hexa-substituted triphenylenes." @default.
- W4362732989 created "2023-04-10" @default.
- W4362732989 creator A5075206902 @default.
- W4362732989 date "2023-04-08" @default.
- W4362732989 modified "2023-10-18" @default.
- W4362732989 title "Spectroscopic and Spectroelectrochemical Studies of Hexapentyloxytriphenylene—A Model Discotic Molecule" @default.
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- W4362732989 doi "https://doi.org/10.3390/ijms24086924" @default.
- W4362732989 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37108088" @default.
- W4362732989 hasPublicationYear "2023" @default.
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