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- W4363677584 abstract "The bond fluctuation model of ionic conductors suggests that the high ionic conductivity is related with the low structural stability of the materials. A physical quantity that is related with the structural stability is the bulk modulus. Some years ago, a microscopic empirical model of bulk modulus has been proposed. The model applied to diverse materials showed a good agreement with the experimental values. It is of considerable interest to verify if such a model works in materials that exhibit high ionic conduction at high temperatures. Our analysis indicates that the temperature dependence of the bulk modulus described by the model is weak when compared with the experimental values. The result indicates that considering merely the effect of thermal expansion is not sufficient to account for the temperature variation of the bulk modulus. In particular, it is shown that such a variation is large in ionic conductors. This observation is interesting from the materials design point of view, because, recent studies consider that the bulk modulus is an important quantity that controls the performance of solid electrolytes. A possible way to extend the model is discussed briefly." @default.
- W4363677584 created "2023-04-11" @default.
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- W4363677584 date "2023-04-01" @default.
- W4363677584 modified "2023-10-14" @default.
- W4363677584 title "Bulk modulus of ionic conductors: A study based on a microscopic empirical model" @default.
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- W4363677584 doi "https://doi.org/10.1016/j.matpr.2023.03.760" @default.
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