Matches in SemOpenAlex for { <https://semopenalex.org/work/W4364352090> ?p ?o ?g. }
- W4364352090 abstract "Since the breakthrough of conductive polymers in 1977, scientists have made great efforts to create small band gap (Eg ) conjugated polymers. Two general strategies to design small Eg conjugated polymers are quinoid structure and donor-acceptor structure. Ultrasmall Eg conjugated polymers (Eg <1.0 eV) always suffer from poor air stability because of high-lying HOMO energy levels. In this work, we report a new strategy to design ultrasmall Eg conjugated polymers by N-B←N unit, i.e. balanced resonant boron-nitrogen covalent bond (B-N) and boron-nitrogen coordination bond (B←N). The resulting polymer exhibits an Eg of 0.82 eV and an onset absorption wavelength of >1500 nm. Moreover, the polymer exhibits excellent air stability because of its low-lying LUMO/HOMO energy levels. An unprecedented property of this polymer is the selective light absorption in the infrared range (800-1500 nm) and high transparency in the visible range (400-780 nm). Using this property, for the first time, we demonstrate the application of conjugated polymers as transparent thermal-shielding coating layer on glass, which reduces indoor solar irradiation through window and consequently reduces power consumption for cooling of buildings and cars in summer." @default.
- W4364352090 created "2023-04-12" @default.
- W4364352090 creator A5014392850 @default.
- W4364352090 creator A5027835055 @default.
- W4364352090 creator A5065069738 @default.
- W4364352090 date "2023-05-05" @default.
- W4364352090 modified "2023-10-17" @default.
- W4364352090 title "Ultra‐Small‐Bandgap Conjugated Polymers Based on an N−B←N Unit" @default.
- W4364352090 cites W1982768268 @default.
- W4364352090 cites W1985365456 @default.
- W4364352090 cites W1986801254 @default.
- W4364352090 cites W1992354154 @default.
- W4364352090 cites W1993209440 @default.
- W4364352090 cites W1999332606 @default.
- W4364352090 cites W2005753285 @default.
- W4364352090 cites W2006038746 @default.
- W4364352090 cites W2013047775 @default.
- W4364352090 cites W2028426531 @default.
- W4364352090 cites W2028735505 @default.
- W4364352090 cites W2034531272 @default.
- W4364352090 cites W2049584904 @default.
- W4364352090 cites W2059044862 @default.
- W4364352090 cites W2071543176 @default.
- W4364352090 cites W2092024458 @default.
- W4364352090 cites W2115059637 @default.
- W4364352090 cites W2159177670 @default.
- W4364352090 cites W2161778416 @default.
- W4364352090 cites W2300256369 @default.
- W4364352090 cites W2314807620 @default.
- W4364352090 cites W2318443662 @default.
- W4364352090 cites W2331778604 @default.
- W4364352090 cites W2357237338 @default.
- W4364352090 cites W2383122722 @default.
- W4364352090 cites W2403634190 @default.
- W4364352090 cites W2468620463 @default.
- W4364352090 cites W2523373923 @default.
- W4364352090 cites W2528066170 @default.
- W4364352090 cites W2754873054 @default.
- W4364352090 cites W2760438221 @default.
- W4364352090 cites W2791853162 @default.
- W4364352090 cites W2888822664 @default.
- W4364352090 cites W2900312972 @default.
- W4364352090 cites W2946089870 @default.
- W4364352090 cites W2951246952 @default.
- W4364352090 cites W2977894221 @default.
- W4364352090 cites W3013160523 @default.
- W4364352090 cites W3019118290 @default.
- W4364352090 cites W3028680184 @default.
- W4364352090 cites W3037001253 @default.
- W4364352090 cites W3043841987 @default.
- W4364352090 cites W3096991041 @default.
- W4364352090 cites W3134664414 @default.
- W4364352090 cites W3153615031 @default.
- W4364352090 cites W3157195325 @default.
- W4364352090 cites W3163905574 @default.
- W4364352090 cites W3170744429 @default.
- W4364352090 cites W3210332802 @default.
- W4364352090 cites W3210353460 @default.
- W4364352090 cites W3217732279 @default.
- W4364352090 cites W4200058826 @default.
- W4364352090 cites W4212976433 @default.
- W4364352090 cites W4220663972 @default.
- W4364352090 cites W4221082588 @default.
- W4364352090 cites W4281684650 @default.
- W4364352090 cites W4282921619 @default.
- W4364352090 cites W4283807066 @default.
- W4364352090 cites W4297855260 @default.
- W4364352090 cites W4308555010 @default.
- W4364352090 doi "https://doi.org/10.1002/anie.202303870" @default.
- W4364352090 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37040127" @default.
- W4364352090 hasPublicationYear "2023" @default.
- W4364352090 type Work @default.
- W4364352090 citedByCount "2" @default.
- W4364352090 crossrefType "journal-article" @default.
- W4364352090 hasAuthorship W4364352090A5014392850 @default.
- W4364352090 hasAuthorship W4364352090A5027835055 @default.
- W4364352090 hasAuthorship W4364352090A5065069738 @default.
- W4364352090 hasConcept C112613896 @default.
- W4364352090 hasConcept C121332964 @default.
- W4364352090 hasConcept C125287762 @default.
- W4364352090 hasConcept C14158195 @default.
- W4364352090 hasConcept C159985019 @default.
- W4364352090 hasConcept C171250308 @default.
- W4364352090 hasConcept C178790620 @default.
- W4364352090 hasConcept C180577832 @default.
- W4364352090 hasConcept C181966813 @default.
- W4364352090 hasConcept C185592680 @default.
- W4364352090 hasConcept C192562407 @default.
- W4364352090 hasConcept C26873012 @default.
- W4364352090 hasConcept C2779892579 @default.
- W4364352090 hasConcept C32909587 @default.
- W4364352090 hasConcept C49040817 @default.
- W4364352090 hasConcept C521977710 @default.
- W4364352090 hasConcept C59061564 @default.
- W4364352090 hasConcept C75473681 @default.
- W4364352090 hasConceptScore W4364352090C112613896 @default.
- W4364352090 hasConceptScore W4364352090C121332964 @default.
- W4364352090 hasConceptScore W4364352090C125287762 @default.
- W4364352090 hasConceptScore W4364352090C14158195 @default.
- W4364352090 hasConceptScore W4364352090C159985019 @default.