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- W4364356063 endingPage "5482" @default.
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- W4364356063 abstract "peri-Acenoacenes are attractive synthetic targets, but their non-benzenoid isomeric counterparts were unnoticed. 1-Ethoxyphenanthro[9,10-e]acephenanthrylene 8 was synthesized and converted to azulene-embedded 9, which is a tribenzo-fused non-alternant isomeric motif of peri-anthracenoanthracene. Aromaticity and single-crystal analyses suggested a formal azulene core for 9, which showed a smaller highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) energy gap with a charge-transfer absorption band and brighter fluorescence than 8 (quantum yield (Φ): 9 = 41.8%, 8 = 8.9%). The reduction potentials of 8 and 9 were nearly identical, and the observations were further supported by density functional theory (DFT) calculations." @default.
- W4364356063 created "2023-04-12" @default.
- W4364356063 creator A5005213491 @default.
- W4364356063 creator A5007434459 @default.
- W4364356063 creator A5023648914 @default.
- W4364356063 creator A5074357528 @default.
- W4364356063 date "2023-04-11" @default.
- W4364356063 modified "2023-10-16" @default.
- W4364356063 title "Constructing 1-Ethoxyphenanthro[9,10-<i>e</i>]acephenanthrylene for the Synthesis of a Polyaromatic Hydrocarbon Containing a Formal Azulene Unit" @default.
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- W4364356063 doi "https://doi.org/10.1021/acs.joc.2c03103" @default.
- W4364356063 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37040656" @default.