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• W4365397796 abstract "Reversibly light and pH dual-responsive spiropyran-based cellulose nanocrystals (SP-CNCs) is synthesized by the attachment of carboxyl-containing spiropyran (SP-COOH) onto cellulose nanocrystals (CNCs). The resulting structure and properties of SP-CNCs are examined by Fourier transform infrared spectroscopy (FT-IR), elemental analysis, transmission electron microscopy (TEM), atomic force microscopy (AFM), dynamic laser light scattering (DSL), ζ-potential measurements and ultraviolet-visible (UV-Vis) light absorption spectroscopy. SP-CNCs exhibit excellent photochromic and photoswitching properties. Spiropyran moieties on SP-CNCs can be switched between open-ring merocyanine (MC) and closed ring spiropyran (SP) forms under UV/Vis irradiation, leading to color changes. Moreover, SP-CNCs display improved photoresponsiveness, photoreversibility, fatigue resistance, and stability in DMSO than in H2O. We further investigate the pH-responsive behavior of SP-CNCs in H2O. SP-CNCs aqueous solution display different colors at different pH values, which can be directly observed by naked eye, indicating that SP-CNCs can function as a visual pH sensor. These results suggest that light and pH dual-responsive SP-CNCs possess great potential for applications in reversible data storage, sensing, optical switching and light-controlled nanomaterials." @default.
• W4365397796 created "2023-04-14" @default.
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• W4365397796 date "2023-01-01" @default.
• W4365397796 modified "2023-10-17" @default.
• W4365397796 title "Light and pH dual-responsive spiropyran-based cellulose nanocrystals" @default.
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• W4365397796 doi "https://doi.org/10.1039/d3ra01637d" @default.
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• W4365397796 hasPublicationYear "2023" @default.
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