Matches in SemOpenAlex for { <https://semopenalex.org/work/W4365457029> ?p ?o ?g. }
- W4365457029 endingPage "118031" @default.
- W4365457029 startingPage "118031" @default.
- W4365457029 abstract "Transition metal- and N-codoped carbon catalysts with low cost are latent substitutes to Pt-based catalysts in oxygen reduction reaction. However, the variety of N species obtained by pyrolysis often makes the determination of the active site controversial. Here, we design catalyst structures with pyrrolic-N anchored dual metal centers, while the presence of pyrrolic-N avoids the complex and variable structure of the active sites. Theory calculations demonstrate that coupling of the Cu–N4 single-atom sites is favorable to reduce the reaction energy barrier of pyrrolic-N-type Fe–N4 active site during the reaction process. Subsequently, the high-purity pyrrolic-N-type iron and copper single-atom catalyst is successfully synthesized to verify the hypothesis. The obtained FeCu–N–C catalyst achieves a half-wave potential of 0.913 V, higher than the 0.839 V of Pt/C. This route may provide new insights for regulating catalytic active sites in high purity pyrrolic-N type catalysts." @default.
- W4365457029 created "2023-04-15" @default.
- W4365457029 creator A5002739525 @default.
- W4365457029 creator A5003360183 @default.
- W4365457029 creator A5007869766 @default.
- W4365457029 creator A5025118942 @default.
- W4365457029 creator A5027800643 @default.
- W4365457029 creator A5032638281 @default.
- W4365457029 creator A5034535783 @default.
- W4365457029 creator A5046524012 @default.
- W4365457029 creator A5048372474 @default.
- W4365457029 creator A5054358636 @default.
- W4365457029 creator A5055399722 @default.
- W4365457029 creator A5081705671 @default.
- W4365457029 creator A5085174785 @default.
- W4365457029 date "2023-06-01" @default.
- W4365457029 modified "2023-10-16" @default.
- W4365457029 title "Introducing dual metal centers in high purity pyrrolic-N for superior oxygen reduction reaction" @default.
- W4365457029 cites W2036113194 @default.
- W4365457029 cites W2104242056 @default.
- W4365457029 cites W2167035995 @default.
- W4365457029 cites W2397627563 @default.
- W4365457029 cites W2531551506 @default.
- W4365457029 cites W2558739653 @default.
- W4365457029 cites W2589074957 @default.
- W4365457029 cites W2608214480 @default.
- W4365457029 cites W2619738972 @default.
- W4365457029 cites W2768340505 @default.
- W4365457029 cites W2808136178 @default.
- W4365457029 cites W2809416657 @default.
- W4365457029 cites W2893269817 @default.
- W4365457029 cites W2915547125 @default.
- W4365457029 cites W2974541005 @default.
- W4365457029 cites W2976567048 @default.
- W4365457029 cites W2981426931 @default.
- W4365457029 cites W2986761410 @default.
- W4365457029 cites W2990194258 @default.
- W4365457029 cites W3006400790 @default.
- W4365457029 cites W3017268781 @default.
- W4365457029 cites W3033926827 @default.
- W4365457029 cites W3036313195 @default.
- W4365457029 cites W3037032211 @default.
- W4365457029 cites W3082544433 @default.
- W4365457029 cites W3088979028 @default.
- W4365457029 cites W3093158599 @default.
- W4365457029 cites W3094286081 @default.
- W4365457029 cites W3094823054 @default.
- W4365457029 cites W3095475868 @default.
- W4365457029 cites W3101327903 @default.
- W4365457029 cites W3111992459 @default.
- W4365457029 cites W3128245296 @default.
- W4365457029 cites W3173963355 @default.
- W4365457029 cites W3175066909 @default.
- W4365457029 cites W3183333374 @default.
- W4365457029 cites W3199614176 @default.
- W4365457029 cites W4200194813 @default.
- W4365457029 cites W4205763560 @default.
- W4365457029 cites W4212798409 @default.
- W4365457029 cites W4213165713 @default.
- W4365457029 cites W4280517210 @default.
- W4365457029 cites W4280564293 @default.
- W4365457029 cites W4289711467 @default.
- W4365457029 cites W4296667447 @default.
- W4365457029 cites W4304185304 @default.
- W4365457029 cites W4322505096 @default.
- W4365457029 doi "https://doi.org/10.1016/j.carbon.2023.118031" @default.
- W4365457029 hasPublicationYear "2023" @default.
- W4365457029 type Work @default.
- W4365457029 citedByCount "1" @default.
- W4365457029 countsByYear W43654570292023 @default.
- W4365457029 crossrefType "journal-article" @default.
- W4365457029 hasAuthorship W4365457029A5002739525 @default.
- W4365457029 hasAuthorship W4365457029A5003360183 @default.
- W4365457029 hasAuthorship W4365457029A5007869766 @default.
- W4365457029 hasAuthorship W4365457029A5025118942 @default.
- W4365457029 hasAuthorship W4365457029A5027800643 @default.
- W4365457029 hasAuthorship W4365457029A5032638281 @default.
- W4365457029 hasAuthorship W4365457029A5034535783 @default.
- W4365457029 hasAuthorship W4365457029A5046524012 @default.
- W4365457029 hasAuthorship W4365457029A5048372474 @default.
- W4365457029 hasAuthorship W4365457029A5054358636 @default.
- W4365457029 hasAuthorship W4365457029A5055399722 @default.
- W4365457029 hasAuthorship W4365457029A5081705671 @default.
- W4365457029 hasAuthorship W4365457029A5085174785 @default.
- W4365457029 hasConcept C104779481 @default.
- W4365457029 hasConcept C106773901 @default.
- W4365457029 hasConcept C140205800 @default.
- W4365457029 hasConcept C149635348 @default.
- W4365457029 hasConcept C159985019 @default.
- W4365457029 hasConcept C161790260 @default.
- W4365457029 hasConcept C178790620 @default.
- W4365457029 hasConcept C179104552 @default.
- W4365457029 hasConcept C185592680 @default.
- W4365457029 hasConcept C192562407 @default.
- W4365457029 hasConcept C36759035 @default.
- W4365457029 hasConcept C41008148 @default.
- W4365457029 hasConcept C540031477 @default.
- W4365457029 hasConcept C544153396 @default.