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• W4365457095 startingPage "1419" @default.
• W4365457095 abstract "Abstract Oximes cause photo‐promoted, copper‐catalyzed N ‐selective arylation with diaryl iodonium salts to produce nitrones, which in turn undergo intra‐ or intermolecular 1,3‐dipolar cyclization with olefins to afford N ‐aryl isoxazolidines. Hypervalent iodine reagents substituted with either electron‐rich or electron‐deficient groups afford the corresponding N ‐aryl isoxazolidines in 26–95% yields. This method offers a faster reaction rate, lower catalyst loading and broader substrate scope of oxime than similar nitrone syntheses employing Chan‐Lam‐Evans coupling. The reaction involves via a radical/single electron transfer (SET) pathway, and does not proceed in the absence of photoirradiation. magnified image" @default.
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• W4365457095 date "2023-04-26" @default.
• W4365457095 modified "2023-10-12" @default.
• W4365457095 title "Synthesis of <i>N</i>‐Aryl Isoxazolidines by Photo‐Promoted <i>N</i>‐Selective Arylation of Oximes and Cyclization Using Hypervalent Iodine Reagents and Copper Catalyst" @default.
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• W4365457095 doi "https://doi.org/10.1002/adsc.202300110" @default.
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