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• W4366083905 abstract "Electrophilic functionalization of N2 moieties in metal dinitrogen complexes typically initiates the catalytic synthesis of N-containing molecules directly from N2. Despite intensive research in the last six decades, how to efficiently and even quantitatively convert N2 into diazenido and hydrazido species still poses a great challenge. In this regard, systematic and comprehensive investigations to elucidate the reaction intricacies are of profound significance. Herein, we report a kinetic dissection on the first and second electrophilic functionalization steps of a new Cr0–N2 system with HOTf, MeOTf, and Me3SiOTf. All reactions pass through fleeting diazenido intermediates and furnish long-lived final hydrazido products, and both steps are quantitative conversions at low temperatures. All of the second-order reaction rates of the first and second transformations were determined as well as the lifetimes of the intervening diazenido species. Based on these findings, we succeeded in large-scale and near-quantitative preparation of all hydrazido species." @default.
• W4366083905 created "2023-04-19" @default.
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• W4366083905 date "2023-04-17" @default.
• W4366083905 modified "2023-10-14" @default.
• W4366083905 title "Snapshots of Early-Stage Quantitative N₂ Electrophilic Functionalization" @default.
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• W4366083905 doi "https://doi.org/10.1021/jacs.3c01497" @default.
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