Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366126875> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W4366126875 abstract "The direct synthesis of sterically hindered aldehydes is highly challenging. Herein, we report a direct approach to generate such compounds via electroreductive cleavage of the C(sp3)-O bond of activated alcohols. Under the established reaction conditions, benzylic radical intermediates were efficiently generated. A subsequent radical-polar crossover generated carbanions that further reacted with N,N-dimethylformamide to form various aldehydes with tertiary or quaternary benzylic carbon centers. The feasibility of a gram-scale synthesis was also demonstrated. This reaction is also operated in a simple undivided cell, which avoids the use of any transition metal catalysts, toxic gas, and reductants." @default.
- W4366126875 created "2023-04-19" @default.
- W4366126875 creator A5008383067 @default.
- W4366126875 creator A5032322155 @default.
- W4366126875 creator A5078640657 @default.
- W4366126875 date "2023-01-01" @default.
- W4366126875 modified "2023-09-30" @default.
- W4366126875 title "Electroreductive formylation of activated alcohols via radical-polar crossover" @default.
- W4366126875 doi "https://doi.org/10.1039/d3cc01529g" @default.
- W4366126875 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37092352" @default.
- W4366126875 hasPublicationYear "2023" @default.
- W4366126875 type Work @default.
- W4366126875 citedByCount "0" @default.
- W4366126875 crossrefType "journal-article" @default.
- W4366126875 hasAuthorship W4366126875A5008383067 @default.
- W4366126875 hasAuthorship W4366126875A5032322155 @default.
- W4366126875 hasAuthorship W4366126875A5078640657 @default.
- W4366126875 hasConcept C106773901 @default.
- W4366126875 hasConcept C121332964 @default.
- W4366126875 hasConcept C1276947 @default.
- W4366126875 hasConcept C161790260 @default.
- W4366126875 hasConcept C178790620 @default.
- W4366126875 hasConcept C185592680 @default.
- W4366126875 hasConcept C201194858 @default.
- W4366126875 hasConcept C21951064 @default.
- W4366126875 hasConcept C2777712214 @default.
- W4366126875 hasConcept C2779155132 @default.
- W4366126875 hasConcept C2780471494 @default.
- W4366126875 hasConcept C29705727 @default.
- W4366126875 hasConcept C3044715 @default.
- W4366126875 hasConcept C75473681 @default.
- W4366126875 hasConcept C82894169 @default.
- W4366126875 hasConceptScore W4366126875C106773901 @default.
- W4366126875 hasConceptScore W4366126875C121332964 @default.
- W4366126875 hasConceptScore W4366126875C1276947 @default.
- W4366126875 hasConceptScore W4366126875C161790260 @default.
- W4366126875 hasConceptScore W4366126875C178790620 @default.
- W4366126875 hasConceptScore W4366126875C185592680 @default.
- W4366126875 hasConceptScore W4366126875C201194858 @default.
- W4366126875 hasConceptScore W4366126875C21951064 @default.
- W4366126875 hasConceptScore W4366126875C2777712214 @default.
- W4366126875 hasConceptScore W4366126875C2779155132 @default.
- W4366126875 hasConceptScore W4366126875C2780471494 @default.
- W4366126875 hasConceptScore W4366126875C29705727 @default.
- W4366126875 hasConceptScore W4366126875C3044715 @default.
- W4366126875 hasConceptScore W4366126875C75473681 @default.
- W4366126875 hasConceptScore W4366126875C82894169 @default.
- W4366126875 hasLocation W43661268751 @default.
- W4366126875 hasLocation W43661268752 @default.
- W4366126875 hasOpenAccess W4366126875 @default.
- W4366126875 hasPrimaryLocation W43661268751 @default.
- W4366126875 hasRelatedWork W2003482293 @default.
- W4366126875 hasRelatedWork W2004112662 @default.
- W4366126875 hasRelatedWork W2004681263 @default.
- W4366126875 hasRelatedWork W2025956931 @default.
- W4366126875 hasRelatedWork W2105639335 @default.
- W4366126875 hasRelatedWork W2312534464 @default.
- W4366126875 hasRelatedWork W2332608447 @default.
- W4366126875 hasRelatedWork W2949366777 @default.
- W4366126875 hasRelatedWork W2952685576 @default.
- W4366126875 hasRelatedWork W2953123074 @default.
- W4366126875 isParatext "false" @default.
- W4366126875 isRetracted "false" @default.
- W4366126875 workType "article" @default.