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- W4366132021 abstract "PEDOT:PSS is one of the most widely used materials as a hole selective layer in organic photovoltaics due to its easy processing and high reproducibility. Unfortunately, the material is limited when testing new donor:acceptor systems due to its intrinsic frontier energy levels which typically leads to energy losses due to inadequate energy level alignment and presence of resistive losses. In this work, PEDOT:PSS:metal phthalocyanines nanocomposite thin films are formulated and used as hole transport layer for organic solar cells (OSCs). PEDOT:PSS is formulated with H2Pc, CuPc, CoPc and ZnPc metal phthalocyanines (MPc) with nanobelt morphology which confers the compatibility with the active layer. Atomic force microscopy (AFM) and x-ray diffraction (XRD) were used to study the morphology and structure of nanocomposite films, respectively. OSCs based on PEDOT:PSS:MPc nanocomposite films were fabricated and the effect of hybrid hole transport layer with various phthalocyanines on photovoltaics properties was studied. Overall, nanocomposition of PEDOT:PSS with metal phthalocyanines improves the final power conversion efficiency of solar cells by 20% by a reduction of the resistive losses due to inadequate energy level alignment. The addition of metal phthalocyanines to PEDOT:PSS is a promising method for tailor-made hole transport materials for new donor:acceptor systems to improve their efficiencies." @default.
- W4366132021 created "2023-04-19" @default.
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- W4366132021 date "2023-05-01" @default.
- W4366132021 modified "2023-10-02" @default.
- W4366132021 title "Nanocomposition of PEDOT:PSS with metal phthalocyanines as promising hole transport layers for organic photovoltaics" @default.
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- W4366132021 doi "https://doi.org/10.1016/j.synthmet.2023.117347" @default.
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