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- W4366156885 abstract "In this study, ZIF-8 metal–organic framework decorated on surface of graphene oxide nanosheets and functionalized with silane moieties ([email protected]) is employed to enhance the anti-corrosion, anti-bacterial, and anti-fouling properties of epoxy coatings modified with polydimethylsiloxane (epoxy-PDMS). The epoxy-PDMS/[email protected] sample has revealed super-hydrophobic behavior with least water contact angle changes (Δθ ≈ 5° while Δθ ≈ 17° is recorded for epoxy-PDMS sample) during 20 days of immersion, twice pull-off adhesion strength (6.8 MPa compared to 3.7 MPa for epoxy-PDMS coating), and significantly higher impedance modulus (8.82 × 108 Ω·cm2 which is 3 times more than the epoxy-PDMS sample) during 60 days of immersion in NaCl electrolyte. The anti-bacterial test against Pseudomonas sp. and anti-fouling monitoring in Qingdao port have shown that fewer bacteria and marine organisms are attached on the epoxy-PDMS/[email protected] coating, respectively, indicating advanced fouling and bacterial resistance of the nanocomposite sample. Based on the theoretical studies by density functional theory (DFT) method, the binding of the components in the [email protected] complex is notably large which could inhibit the penetration of corrosive agents toward the steel substrate. In addition, the stabilization of the [email protected] nanohybrid is mainly controlled through van der Waals (vdW) forces." @default.
- W4366156885 created "2023-04-19" @default.
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- W4366156885 date "2023-06-01" @default.
- W4366156885 modified "2023-09-26" @default.
- W4366156885 title "Multi-treatments based on polydimethylsiloxane and metal-organic framework wrapped with graphene oxide for achieving long-term corrosion and fouling protection: experimental and density functional theory aspects" @default.
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- W4366156885 doi "https://doi.org/10.1016/j.conbuildmat.2023.131229" @default.
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