Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366241608> ?p ?o ?g. }
- W4366241608 abstract "Abstract Ketones are among the most useful functional groups in organic synthesis, and they are commonly encountered in a broad range of compounds with various applications. Herein, we describe the mesoionic carbene‐catalyzed coupling reaction of aldehydes with non‐activated secondary and even primary alkyl halides. This metal‐free method utilizes deprotonated Breslow intermediates derived from mesoionic carbenes (MICs), which act as super electron donors and induce the single‐electron reduction of alkyl halides. This mild coupling reaction has a broad substrate scope and tolerates many functional groups, which allows to prepare a diversity of simple ketones as well as bio‐active molecules by late‐stage functionalization." @default.
- W4366241608 created "2023-04-20" @default.
- W4366241608 creator A5019278344 @default.
- W4366241608 creator A5022256556 @default.
- W4366241608 creator A5032470395 @default.
- W4366241608 creator A5057672142 @default.
- W4366241608 creator A5061127427 @default.
- W4366241608 date "2023-05-08" @default.
- W4366241608 modified "2023-10-18" @default.
- W4366241608 title "Mesoionic Carbene‐Catalyzed Formyl Alkylation of Aldehydes" @default.
- W4366241608 cites W1978890358 @default.
- W4366241608 cites W1988289713 @default.
- W4366241608 cites W2000120698 @default.
- W4366241608 cites W2003555872 @default.
- W4366241608 cites W2022670739 @default.
- W4366241608 cites W2023913818 @default.
- W4366241608 cites W2025853617 @default.
- W4366241608 cites W2026655781 @default.
- W4366241608 cites W2026721392 @default.
- W4366241608 cites W2038092103 @default.
- W4366241608 cites W2067474966 @default.
- W4366241608 cites W2077589208 @default.
- W4366241608 cites W2079806904 @default.
- W4366241608 cites W2083357654 @default.
- W4366241608 cites W2094871139 @default.
- W4366241608 cites W2107167062 @default.
- W4366241608 cites W2112485861 @default.
- W4366241608 cites W2118289930 @default.
- W4366241608 cites W2122031375 @default.
- W4366241608 cites W2143036996 @default.
- W4366241608 cites W2162662232 @default.
- W4366241608 cites W2162846787 @default.
- W4366241608 cites W2163114649 @default.
- W4366241608 cites W2299637886 @default.
- W4366241608 cites W2313856024 @default.
- W4366241608 cites W2320163706 @default.
- W4366241608 cites W2506748349 @default.
- W4366241608 cites W2514462360 @default.
- W4366241608 cites W2520813356 @default.
- W4366241608 cites W2612498535 @default.
- W4366241608 cites W2744092316 @default.
- W4366241608 cites W2900922487 @default.
- W4366241608 cites W2903777026 @default.
- W4366241608 cites W2915743380 @default.
- W4366241608 cites W2947141118 @default.
- W4366241608 cites W2970991365 @default.
- W4366241608 cites W2973191462 @default.
- W4366241608 cites W2988908382 @default.
- W4366241608 cites W3007749984 @default.
- W4366241608 cites W3009123515 @default.
- W4366241608 cites W3009496489 @default.
- W4366241608 cites W3020976311 @default.
- W4366241608 cites W3022540046 @default.
- W4366241608 cites W3032414634 @default.
- W4366241608 cites W3045095995 @default.
- W4366241608 cites W3047914721 @default.
- W4366241608 cites W3048647494 @default.
- W4366241608 cites W3075119080 @default.
- W4366241608 cites W3091483831 @default.
- W4366241608 cites W3136715343 @default.
- W4366241608 cites W3144342301 @default.
- W4366241608 cites W3152410730 @default.
- W4366241608 cites W3162642407 @default.
- W4366241608 cites W3168625956 @default.
- W4366241608 cites W3197903425 @default.
- W4366241608 cites W3204066891 @default.
- W4366241608 cites W3206787077 @default.
- W4366241608 cites W3207871969 @default.
- W4366241608 cites W4211259676 @default.
- W4366241608 cites W4214934459 @default.
- W4366241608 cites W4220713817 @default.
- W4366241608 cites W4221001123 @default.
- W4366241608 cites W4296286003 @default.
- W4366241608 cites W4298140149 @default.
- W4366241608 cites W4300555443 @default.
- W4366241608 cites W4307570625 @default.
- W4366241608 cites W4313946435 @default.
- W4366241608 cites W4318694601 @default.
- W4366241608 doi "https://doi.org/10.1002/anie.202303478" @default.
- W4366241608 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37070460" @default.
- W4366241608 hasPublicationYear "2023" @default.
- W4366241608 type Work @default.
- W4366241608 citedByCount "7" @default.
- W4366241608 countsByYear W43662416082023 @default.
- W4366241608 crossrefType "journal-article" @default.
- W4366241608 hasAuthorship W4366241608A5019278344 @default.
- W4366241608 hasAuthorship W4366241608A5022256556 @default.
- W4366241608 hasAuthorship W4366241608A5032470395 @default.
- W4366241608 hasAuthorship W4366241608A5057672142 @default.
- W4366241608 hasAuthorship W4366241608A5061127427 @default.
- W4366241608 hasConcept C111368507 @default.
- W4366241608 hasConcept C118629725 @default.
- W4366241608 hasConcept C127313418 @default.
- W4366241608 hasConcept C142724271 @default.
- W4366241608 hasConcept C145148216 @default.
- W4366241608 hasConcept C161790260 @default.
- W4366241608 hasConcept C164361826 @default.
- W4366241608 hasConcept C171560689 @default.
- W4366241608 hasConcept C178790620 @default.
- W4366241608 hasConcept C185592680 @default.