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- W4366262802 abstract "Heterometallic Cu−In and Cu−Ga complex salts, [Cu(III)(dedtc)2][In(III)Cl4] (1) and [Cu(III)(dedtc)2][Ga(III)Cl4] (2) (dedtc = −S2CNEt2, diethyldithiocarbamate), were synthesized from Cu(II)(dedtc)2, In(III)Cl3, and Ga(III)I3 in dichloromethane and acetone solvents. The trivalent copper complex [Cu(III)(dedtc)2]+ was produced by an oxidation reaction of Cu(II)(dedtc)2 and [M(III)Cl4]– (M = In, Ga) which exhibit a blue-shift of the C–N vibrational mode resulting from the high oxidation state of copper(III) cations. In the Cu−Ga complex salt (2), [Ga(III)Cl4]– was obtained by a halogen exchange reaction between Ga(III)I3 and CH2Cl2. Cu−In and Cu−Ga complex single crystals were grown in benzene and dichloromethane media. Their crystal structures were confirmed that [Cu(III)(dedtc)2]+ units formed distorted octahedral structures with infinite polymeric Cu–S chains surrounded by dimeric [M(III)Cl4]– and benzene. The crystal structures of 1 and 2 included benzene as a guest molecule due to strong noncovalent interactions of metal chloride anions." @default.
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- W4366262802 date "2023-08-01" @default.
- W4366262802 modified "2023-10-18" @default.
- W4366262802 title "Heterometallic complexes of trivalent copper dithiocarbamate with indium and gallium chloride" @default.
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- W4366262802 doi "https://doi.org/10.1016/j.molstruc.2023.135588" @default.
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