Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366271013> ?p ?o ?g. }
- W4366271013 endingPage "7859" @default.
- W4366271013 startingPage "7852" @default.
- W4366271013 abstract "Chirality effects are well documented in different biological functions, but examples in soft materials physics are lesser known. This paper reports a significant chirality effect on modulating ferroelectricity in hydrogen-bonded supramolecular assemblies of two acceptor (A)–donor (D)–acceptor (A)-type conjugated molecules, namely, AD2A-C and AD2A. Both molecules contain the same naphthalimide–bithiophene–naphthalimide conjugated chromophore, symmetrically functionalized with two substituted benzamide wedges with either a chiral (AD2A-C) or achiral (AD2A) peripheral alkyl chain. They exhibit self-assembly in a hydrocarbon solvent methylcyclohexane (MCH), driven by H-bonding among the amide groups and aromatic stacking of the conjugated chromophore. Despite showing similar entangled fibrillar morphology, ultraviolet–visible (UV–vis) and Fourier transform infrared spectroscopy (FT-IR) spectra of the aggregated samples indicate a significant difference in the internal order of the self-assembled AD2A-C and AD2A. The CD spectra and microscopy images confirm helical assembly for the chiral derivative. In the mixed samples of AD2A-C + AD2A, chirality induction followed a “sergeant and soldiers” principle. The chiral AD2A-C exhibits stable ferroelectricity with a Curie temperature of 361 K and a saturation polarization of ∼2 μC cm–2, while the achiral AD2A lacks any notable ferroelectricity. The retained ferroelectricity in the mixed samples and the polarization tunability through chirality induction support their direct correlation and are key observations for predicting the future soft ferroelectric low-power electronic systems." @default.
- W4366271013 created "2023-04-20" @default.
- W4366271013 creator A5000195088 @default.
- W4366271013 creator A5046722298 @default.
- W4366271013 creator A5056895049 @default.
- W4366271013 creator A5060000490 @default.
- W4366271013 creator A5061188178 @default.
- W4366271013 date "2023-04-18" @default.
- W4366271013 modified "2023-10-14" @default.
- W4366271013 title "Pronounced Chirality Effect on the Ferroelectricity of Hydrogen-Bonded Supramolecular Assemblies of Ambipolar Chromophoric Systems" @default.
- W4366271013 cites W146254884 @default.
- W4366271013 cites W1826734676 @default.
- W4366271013 cites W1963740321 @default.
- W4366271013 cites W1968219762 @default.
- W4366271013 cites W1982643031 @default.
- W4366271013 cites W2006840690 @default.
- W4366271013 cites W2025113154 @default.
- W4366271013 cites W2037009864 @default.
- W4366271013 cites W2043500368 @default.
- W4366271013 cites W2050042127 @default.
- W4366271013 cites W2058980730 @default.
- W4366271013 cites W2094923026 @default.
- W4366271013 cites W2100849404 @default.
- W4366271013 cites W2329551239 @default.
- W4366271013 cites W2441938696 @default.
- W4366271013 cites W2555541385 @default.
- W4366271013 cites W2562419925 @default.
- W4366271013 cites W2620700726 @default.
- W4366271013 cites W2725434996 @default.
- W4366271013 cites W2757431502 @default.
- W4366271013 cites W2769130656 @default.
- W4366271013 cites W2901104759 @default.
- W4366271013 cites W2908861435 @default.
- W4366271013 cites W2913432046 @default.
- W4366271013 cites W2948644625 @default.
- W4366271013 cites W2954263663 @default.
- W4366271013 cites W3005330665 @default.
- W4366271013 cites W3021109768 @default.
- W4366271013 cites W3022090206 @default.
- W4366271013 cites W3025268895 @default.
- W4366271013 cites W3043160647 @default.
- W4366271013 cites W3085588687 @default.
- W4366271013 cites W3102578762 @default.
- W4366271013 cites W3110906444 @default.
- W4366271013 cites W3143351974 @default.
- W4366271013 cites W3195783684 @default.
- W4366271013 cites W3202221221 @default.
- W4366271013 cites W4200306827 @default.
- W4366271013 cites W4205874676 @default.
- W4366271013 cites W4206224640 @default.
- W4366271013 cites W4211152447 @default.
- W4366271013 cites W4211200593 @default.
- W4366271013 cites W4213233750 @default.
- W4366271013 cites W4292621946 @default.
- W4366271013 cites W4302761328 @default.
- W4366271013 cites W4309269213 @default.
- W4366271013 doi "https://doi.org/10.1021/acs.jpcc.3c00511" @default.
- W4366271013 hasPublicationYear "2023" @default.
- W4366271013 type Work @default.
- W4366271013 citedByCount "1" @default.
- W4366271013 countsByYear W43662710132023 @default.
- W4366271013 crossrefType "journal-article" @default.
- W4366271013 hasAuthorship W4366271013A5000195088 @default.
- W4366271013 hasAuthorship W4366271013A5046722298 @default.
- W4366271013 hasAuthorship W4366271013A5056895049 @default.
- W4366271013 hasAuthorship W4366271013A5060000490 @default.
- W4366271013 hasAuthorship W4366271013A5061188178 @default.
- W4366271013 hasConcept C112613896 @default.
- W4366271013 hasConcept C115624301 @default.
- W4366271013 hasConcept C121332964 @default.
- W4366271013 hasConcept C124668440 @default.
- W4366271013 hasConcept C133386390 @default.
- W4366271013 hasConcept C178790620 @default.
- W4366271013 hasConcept C185592680 @default.
- W4366271013 hasConcept C192468462 @default.
- W4366271013 hasConcept C192562407 @default.
- W4366271013 hasConcept C20621625 @default.
- W4366271013 hasConcept C2777527944 @default.
- W4366271013 hasConcept C2780263894 @default.
- W4366271013 hasConcept C49040817 @default.
- W4366271013 hasConcept C521977710 @default.
- W4366271013 hasConcept C52703039 @default.
- W4366271013 hasConcept C62520636 @default.
- W4366271013 hasConcept C75473681 @default.
- W4366271013 hasConcept C7602139 @default.
- W4366271013 hasConcept C79090758 @default.
- W4366271013 hasConcept C8010536 @default.
- W4366271013 hasConcept C93275456 @default.
- W4366271013 hasConceptScore W4366271013C112613896 @default.
- W4366271013 hasConceptScore W4366271013C115624301 @default.
- W4366271013 hasConceptScore W4366271013C121332964 @default.
- W4366271013 hasConceptScore W4366271013C124668440 @default.
- W4366271013 hasConceptScore W4366271013C133386390 @default.
- W4366271013 hasConceptScore W4366271013C178790620 @default.
- W4366271013 hasConceptScore W4366271013C185592680 @default.
- W4366271013 hasConceptScore W4366271013C192468462 @default.
- W4366271013 hasConceptScore W4366271013C192562407 @default.
- W4366271013 hasConceptScore W4366271013C20621625 @default.