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- W4366293997 abstract "In the present study, a cobalt-doped catalyst was prepared from chicken eggshell powder (CEP) biowaste to be used in the hydrolysis of sodium borohydride (NaBH4). In the presence of the prepared catalyst (CEPcat), possible effects of the parameters of NaOH concentration (%), catalyst amount (g), NaBH4 concentration (%), process temperature (oC) and reusability affecting the hydrolysis of sodium borohydride were examined. The CEPcat obtained was characterized with FT-IR, TGA, XRD, SEM and EDX analyses. The hydrogen generation rate (HGR) was determined as 432 mL gCo−1 min−1 in the presence of 1 g CEPcat, a CoO/CaO ratio of 10/90 and 1% NaBH4 concentration. The activation energy of the NaBH4 hydrolysis reaction was calculated as 16.78 kJ mol−1. After 16 reuses of the CEPcat there was no significant decrease in the hydrogen volume. Compared to the first use while there was an increase in the HGR. These results showed that the CEPcat prepared has a significant advantage over other catalysts for use in NaBH4 hydrolysis." @default.
- W4366293997 created "2023-04-20" @default.
- W4366293997 creator A5015372329 @default.
- W4366293997 creator A5082736659 @default.
- W4366293997 date "2023-08-01" @default.
- W4366293997 modified "2023-10-02" @default.
- W4366293997 title "Synthesis of cobalt-doped catalyst for NaBH4 hydrolysis using eggshell biowaste" @default.
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- W4366293997 doi "https://doi.org/10.1016/j.ijhydene.2023.04.047" @default.
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