Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366351360> ?p ?o ?g. }
- W4366351360 abstract "Abstract Controlling diamond structures with nanometer precision is fundamentally challenging owing to their extreme and far‐from‐equilibrium synthetic conditions. State‐of‐the‐art techniques, including detonation, chemical vapor deposition, mechanical grinding, and high‐pressure‐high‐temperature synthesis, yield nanodiamond particles with a broad distribution of sizes. Despite many efforts, the direct synthesis of nanodiamonds with precisely controlled diameters remains elusive. Here the geochemistry‐inspired synthesis of sub‐5 nm nanodiamonds with sub‐nanometer size deviation is described. High‐pressure‐high‐temperature treatment of uniform iron carbide nanoparticles embedded in iron oxide matrices yields nanodiamonds with tunable diameters down to 2.13 and 0.22 nm standard deviation. A self‐limiting, redox‐driven, and diffusion‐controlled solid‐state reaction mechanism is proposed and supported by in situ X‐ray diffraction, ex situ characterizations, and computational modeling. This work provides a unique mechanism for the precise control of nanostructured diamonds under extreme conditions and paves the road for the full realization of their potential in emerging technologies." @default.
- W4366351360 created "2023-04-21" @default.
- W4366351360 creator A5015083844 @default.
- W4366351360 creator A5016107458 @default.
- W4366351360 creator A5020667195 @default.
- W4366351360 creator A5025627668 @default.
- W4366351360 creator A5026108001 @default.
- W4366351360 creator A5027816480 @default.
- W4366351360 creator A5042562279 @default.
- W4366351360 creator A5042638113 @default.
- W4366351360 creator A5051021779 @default.
- W4366351360 creator A5051492650 @default.
- W4366351360 creator A5057153132 @default.
- W4366351360 creator A5067740646 @default.
- W4366351360 creator A5073613442 @default.
- W4366351360 creator A5083304846 @default.
- W4366351360 creator A5089497883 @default.
- W4366351360 creator A5089864509 @default.
- W4366351360 date "2023-04-18" @default.
- W4366351360 modified "2023-10-14" @default.
- W4366351360 title "Self‐Limiting Sub‐5 nm Nanodiamonds by Geochemistry‐Inspired Synthesis" @default.
- W4366351360 cites W1938770084 @default.
- W4366351360 cites W1968204255 @default.
- W4366351360 cites W1974760047 @default.
- W4366351360 cites W1978740094 @default.
- W4366351360 cites W1986604949 @default.
- W4366351360 cites W1987380131 @default.
- W4366351360 cites W1988469553 @default.
- W4366351360 cites W1989717037 @default.
- W4366351360 cites W1997155563 @default.
- W4366351360 cites W2006842594 @default.
- W4366351360 cites W2012169356 @default.
- W4366351360 cites W2014174828 @default.
- W4366351360 cites W2015390878 @default.
- W4366351360 cites W2018072842 @default.
- W4366351360 cites W2036369217 @default.
- W4366351360 cites W2055022226 @default.
- W4366351360 cites W2056737213 @default.
- W4366351360 cites W2064829539 @default.
- W4366351360 cites W2067924579 @default.
- W4366351360 cites W2068778288 @default.
- W4366351360 cites W2092012288 @default.
- W4366351360 cites W2094816534 @default.
- W4366351360 cites W2099540110 @default.
- W4366351360 cites W2102244387 @default.
- W4366351360 cites W2133767809 @default.
- W4366351360 cites W2257763509 @default.
- W4366351360 cites W2262992553 @default.
- W4366351360 cites W2278631255 @default.
- W4366351360 cites W2399429321 @default.
- W4366351360 cites W2418560736 @default.
- W4366351360 cites W2426402959 @default.
- W4366351360 cites W2460858871 @default.
- W4366351360 cites W2513933746 @default.
- W4366351360 cites W2559477175 @default.
- W4366351360 cites W2586252440 @default.
- W4366351360 cites W2591322181 @default.
- W4366351360 cites W2746624171 @default.
- W4366351360 cites W2779959842 @default.
- W4366351360 cites W2792746703 @default.
- W4366351360 cites W2883355388 @default.
- W4366351360 cites W2883877975 @default.
- W4366351360 cites W2885561267 @default.
- W4366351360 cites W2896377917 @default.
- W4366351360 cites W2947631725 @default.
- W4366351360 cites W2962884620 @default.
- W4366351360 cites W2971011432 @default.
- W4366351360 cites W2979214696 @default.
- W4366351360 cites W2986413343 @default.
- W4366351360 cites W3007340931 @default.
- W4366351360 cites W3021825133 @default.
- W4366351360 cites W3100477823 @default.
- W4366351360 cites W3127837139 @default.
- W4366351360 cites W4295063373 @default.
- W4366351360 cites W4313680637 @default.
- W4366351360 cites W962313638 @default.
- W4366351360 doi "https://doi.org/10.1002/smll.202300659" @default.
- W4366351360 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37072896" @default.
- W4366351360 hasPublicationYear "2023" @default.
- W4366351360 type Work @default.
- W4366351360 citedByCount "1" @default.
- W4366351360 countsByYear W43663513602023 @default.
- W4366351360 crossrefType "journal-article" @default.
- W4366351360 hasAuthorship W4366351360A5015083844 @default.
- W4366351360 hasAuthorship W4366351360A5016107458 @default.
- W4366351360 hasAuthorship W4366351360A5020667195 @default.
- W4366351360 hasAuthorship W4366351360A5025627668 @default.
- W4366351360 hasAuthorship W4366351360A5026108001 @default.
- W4366351360 hasAuthorship W4366351360A5027816480 @default.
- W4366351360 hasAuthorship W4366351360A5042562279 @default.
- W4366351360 hasAuthorship W4366351360A5042638113 @default.
- W4366351360 hasAuthorship W4366351360A5051021779 @default.
- W4366351360 hasAuthorship W4366351360A5051492650 @default.
- W4366351360 hasAuthorship W4366351360A5057153132 @default.
- W4366351360 hasAuthorship W4366351360A5067740646 @default.
- W4366351360 hasAuthorship W4366351360A5073613442 @default.
- W4366351360 hasAuthorship W4366351360A5083304846 @default.
- W4366351360 hasAuthorship W4366351360A5089497883 @default.
- W4366351360 hasAuthorship W4366351360A5089864509 @default.
- W4366351360 hasConcept C127413603 @default.