FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366351656> ?p ?o ?g. }

• W4366351656 endingPage "8510" @default.
• W4366351656 startingPage "8499" @default.
• W4366351656 abstract "Heterogenous Pd catalysts play a pivotal role in the chemical industry; however, it is plagued by S2- or other strong adsorbates inducing surface poisoning long term. Herein, we report the development of AuFe3@Pd/γ-Fe2O3 nanosheets (NSs) as an in situ regenerable and highly active hydrogenation catalyst. Upon poisoning, the Pd monolayer sites could be fully and oxidatively regenerated under ambient conditions, which is initiated by •OH radicals from surface defect/FeTetra vacancy-rich γ-Fe2O3 NSs via the Fenton-like pathway. Both experimental and theoretical analyses demonstrate that for the electronic and geometric effect, the 2-3 nm AuFe3 intermetallic nanocluster core promotes the adsorption of reactant onto Pd sites; in addition, it lowers Pd's affinity for •OH radicals to enhance their stability during oxidative regeneration. When packed into a quartz sand fixed-bed catalyst column, the AuFe3@Pd/γ-Fe2O3 NSs are highly active in hydrogenating the carbon-halogen bond, which comprises a crucial step for the removal of micropollutants in drinking water and recovery of resources from heavily polluted wastewater, and withstand ten rounds of regeneration. By maximizing the use of ultrathin metal oxide NSs and intermetallic nanocluster and monolayer Pd, the current study demonstrates a comprehensive strategy for developing sustainable Pd catalysts for liquid catalysis." @default.
• W4366351656 created "2023-04-21" @default.
• W4366351656 creator A5000403810 @default.
• W4366351656 creator A5015563169 @default.
• W4366351656 creator A5031603630 @default.
• W4366351656 creator A5035393368 @default.
• W4366351656 creator A5046772439 @default.
• W4366351656 creator A5052126630 @default.
• W4366351656 creator A5059390739 @default.
• W4366351656 creator A5061534629 @default.
• W4366351656 creator A5084622213 @default.
• W4366351656 creator A5088572772 @default.
• W4366351656 date "2023-04-19" @default.
• W4366351656 modified "2023-10-13" @default.
• W4366351656 title "AuFe₃@Pd/γ-Fe₂O₃ Nanosheets as an In Situ Regenerable and Highly Efficient Hydrogenation Catalyst" @default.
• W4366351656 cites W1841119910 @default.
• W4366351656 cites W1966660645 @default.
• W4366351656 cites W1987905130 @default.
• W4366351656 cites W1990099676 @default.
• W4366351656 cites W2006170424 @default.
• W4366351656 cites W2017196167 @default.
• W4366351656 cites W2029842534 @default.
• W4366351656 cites W2033270806 @default.
• W4366351656 cites W2054704030 @default.
• W4366351656 cites W2056507429 @default.
• W4366351656 cites W2059795417 @default.
• W4366351656 cites W2070227796 @default.
• W4366351656 cites W2083222334 @default.
• W4366351656 cites W2090452985 @default.
• W4366351656 cites W2114244507 @default.
• W4366351656 cites W2140581565 @default.
• W4366351656 cites W2170913114 @default.
• W4366351656 cites W2202132379 @default.
• W4366351656 cites W2356997838 @default.
• W4366351656 cites W2513165742 @default.
• W4366351656 cites W2596263195 @default.
• W4366351656 cites W2609555750 @default.
• W4366351656 cites W2788210753 @default.
• W4366351656 cites W2790011443 @default.
• W4366351656 cites W2793503277 @default.
• W4366351656 cites W2796726085 @default.
• W4366351656 cites W2806370073 @default.
• W4366351656 cites W2807874136 @default.
• W4366351656 cites W2811495724 @default.
• W4366351656 cites W2860842684 @default.
• W4366351656 cites W2888827392 @default.
• W4366351656 cites W2892154251 @default.
• W4366351656 cites W2963437926 @default.
• W4366351656 cites W2989442269 @default.
• W4366351656 cites W2990505453 @default.
• W4366351656 cites W3034300274 @default.
• W4366351656 cites W3036572428 @default.
• W4366351656 cites W3038025793 @default.
• W4366351656 cites W3087240806 @default.
• W4366351656 cites W3101544822 @default.
• W4366351656 cites W3128883496 @default.
• W4366351656 cites W3135979058 @default.
• W4366351656 cites W3160292980 @default.
• W4366351656 cites W3192838056 @default.
• W4366351656 cites W3198276978 @default.
• W4366351656 cites W3206986155 @default.
• W4366351656 cites W3207230365 @default.
• W4366351656 cites W4200507044 @default.
• W4366351656 cites W4205869773 @default.
• W4366351656 cites W4206045395 @default.
• W4366351656 cites W4210610274 @default.
• W4366351656 cites W4210662194 @default.
• W4366351656 cites W4220937537 @default.
• W4366351656 cites W4223929231 @default.
• W4366351656 cites W4229055861 @default.
• W4366351656 cites W4235062206 @default.
• W4366351656 cites W4283696634 @default.
• W4366351656 doi "https://doi.org/10.1021/acsnano.3c00745" @default.
• W4366351656 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37074122" @default.
• W4366351656 hasPublicationYear "2023" @default.
• W4366351656 type Work @default.
• W4366351656 citedByCount "0" @default.
• W4366351656 crossrefType "journal-article" @default.
• W4366351656 hasAuthorship W4366351656A5000403810 @default.
• W4366351656 hasAuthorship W4366351656A5015563169 @default.
• W4366351656 hasAuthorship W4366351656A5031603630 @default.
• W4366351656 hasAuthorship W4366351656A5035393368 @default.
• W4366351656 hasAuthorship W4366351656A5046772439 @default.
• W4366351656 hasAuthorship W4366351656A5052126630 @default.
• W4366351656 hasAuthorship W4366351656A5059390739 @default.
• W4366351656 hasAuthorship W4366351656A5061534629 @default.
• W4366351656 hasAuthorship W4366351656A5084622213 @default.
• W4366351656 hasAuthorship W4366351656A5088572772 @default.
• W4366351656 hasConcept C106773901 @default.
• W4366351656 hasConcept C127413603 @default.
• W4366351656 hasConcept C139066938 @default.
• W4366351656 hasConcept C150394285 @default.
• W4366351656 hasConcept C161790260 @default.
• W4366351656 hasConcept C171250308 @default.
• W4366351656 hasConcept C178790620 @default.
• W4366351656 hasConcept C179104552 @default.
• W4366351656 hasConcept C185592680 @default.
• W4366351656 hasConcept C191897082 @default.

• next