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• W4366380249 abstract "We designed and synthesized a new tripyridine dipyrrolide pincer ligand, which could be doubly deprotonated to provide five-nitrogen-donor sites and then utilized to prepare a subnanometric chiral silver cluster. The cluster belongs to an S4 point group and shows a double-stranded helicate. DFT calculations were performed to analyze the electronic structure of the cluster. Interestingly, through hierarchical intercluster interactions, the cluster helicates evolve into complex secondary structures including a right-handed helix and a folded sheet, both of which are reminiscent of secondary structures of proteins, i.e., an α-helix and an antiparallel β-sheet." @default.
• W4366380249 created "2023-04-21" @default.
• W4366380249 creator A5006464161 @default.
• W4366380249 creator A5071442542 @default.
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• W4366380249 date "2023-01-01" @default.
• W4366380249 modified "2023-10-01" @default.
• W4366380249 title "Secondary hierarchical complexity in double-stranded cluster helicates covered by NNNNN type pincer ligands" @default.
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• W4366380249 doi "https://doi.org/10.1039/d3dt00912b" @default.
• W4366380249 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37128862" @default.
• W4366380249 hasPublicationYear "2023" @default.
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