FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366385236> ?p ?o ?g. }

• W4366385236 endingPage "113160" @default.
• W4366385236 startingPage "113160" @default.
• W4366385236 abstract "Because the high electron cloud density around Ru is favorable for ammonia decomposition, gallium addition to it resulted in an alkaline molecular sieve carrier with a large specific surface area. It was revealed that GaOH not only elevated the electron cloud density near the active center of Ru but also encouraged NH bond breaking and hydrogen atoms’ binding on the catalyst surface. Furthermore, the molecular sieve's regular pore structure strongly inhibited the growth of Ru particles within it, resulting in a high degree of mono-dispersion of Ru nanoparticles and a reduction in the average particle size of the Ru active center to < 3 nm. For TOF >1, the above two factors combined to decrease the ammonia decomposition temperature to < 450 °C. Furthermore, under photothermal synergistic catalysis, the hydrogen production rate via ammonia decomposition was further elevated, and the reaction temperature was further decreased to < 380 °C with TOF > 1. In situ UV photoelectron spectroscopy clarified that the hydrogen atom concentration on Ru increased during photothermal catalysis. According to the FT-IR analysis of the surface intermediate of NH/NH2 formed by ammonia decomposition, photothermal synergistic catalysis can weaken the NH bond compared with pure heating, making it easier for H atoms to combine and form H2. The test results of the correlation between activation energy, reaction rate, and ammonia partial pressure show that, when compared to pure thermal catalysis, photothermal catalysis does not substantially alter the reaction path. The primary reason behind the increased hydrogen production rate of ammonia decomposition by photothermal catalysis was the thermal effect of the light source." @default.
• W4366385236 created "2023-04-21" @default.
• W4366385236 creator A5018814025 @default.
• W4366385236 creator A5032561297 @default.
• W4366385236 creator A5058010200 @default.
• W4366385236 creator A5060181405 @default.
• W4366385236 creator A5060898939 @default.
• W4366385236 creator A5082373596 @default.
• W4366385236 date "2023-06-01" @default.
• W4366385236 modified "2023-09-25" @default.
• W4366385236 title "Hydrogen production from ammonia decomposition catalyzed by Ru nano-particles in alkaline molecular sieves under photothermal conditions" @default.
• W4366385236 cites W1967991158 @default.
• W4366385236 cites W1970127494 @default.
• W4366385236 cites W1977129513 @default.
• W4366385236 cites W1981855787 @default.
• W4366385236 cites W1988846397 @default.
• W4366385236 cites W1997793091 @default.
• W4366385236 cites W2002122829 @default.
• W4366385236 cites W2004577952 @default.
• W4366385236 cites W2007395042 @default.
• W4366385236 cites W2011195878 @default.
• W4366385236 cites W2011769639 @default.
• W4366385236 cites W2033129967 @default.
• W4366385236 cites W2044915962 @default.
• W4366385236 cites W2059334224 @default.
• W4366385236 cites W2083748517 @default.
• W4366385236 cites W2125062290 @default.
• W4366385236 cites W2138958945 @default.
• W4366385236 cites W2151136774 @default.
• W4366385236 cites W2159314958 @default.
• W4366385236 cites W2230046744 @default.
• W4366385236 cites W2321083195 @default.
• W4366385236 cites W2326896391 @default.
• W4366385236 cites W2518988237 @default.
• W4366385236 cites W2605821874 @default.
• W4366385236 cites W2625361379 @default.
• W4366385236 cites W2772914689 @default.
• W4366385236 cites W2793503484 @default.
• W4366385236 cites W2917082907 @default.
• W4366385236 cites W2951226029 @default.
• W4366385236 cites W2972052805 @default.
• W4366385236 cites W2980642647 @default.
• W4366385236 cites W2986805888 @default.
• W4366385236 cites W2995574350 @default.
• W4366385236 cites W3117384749 @default.
• W4366385236 cites W3120836419 @default.
• W4366385236 cites W3157712877 @default.
• W4366385236 cites W3165100702 @default.
• W4366385236 cites W3206606417 @default.
• W4366385236 cites W3213776010 @default.
• W4366385236 cites W4221094270 @default.
• W4366385236 cites W4291746133 @default.
• W4366385236 cites W4292818995 @default.
• W4366385236 cites W4295406682 @default.
• W4366385236 doi "https://doi.org/10.1016/j.mcat.2023.113160" @default.
• W4366385236 hasPublicationYear "2023" @default.
• W4366385236 type Work @default.
• W4366385236 citedByCount "0" @default.
• W4366385236 crossrefType "journal-article" @default.
• W4366385236 hasAuthorship W4366385236A5018814025 @default.
• W4366385236 hasAuthorship W4366385236A5032561297 @default.
• W4366385236 hasAuthorship W4366385236A5058010200 @default.
• W4366385236 hasAuthorship W4366385236A5060181405 @default.
• W4366385236 hasAuthorship W4366385236A5060898939 @default.
• W4366385236 hasAuthorship W4366385236A5082373596 @default.
• W4366385236 hasConcept C105281773 @default.
• W4366385236 hasConcept C124681953 @default.
• W4366385236 hasConcept C155672457 @default.
• W4366385236 hasConcept C160434732 @default.
• W4366385236 hasConcept C161790260 @default.
• W4366385236 hasConcept C171250308 @default.
• W4366385236 hasConcept C178790620 @default.
• W4366385236 hasConcept C179104552 @default.
• W4366385236 hasConcept C181258405 @default.
• W4366385236 hasConcept C182606246 @default.
• W4366385236 hasConcept C185592680 @default.
• W4366385236 hasConcept C192562407 @default.
• W4366385236 hasConcept C202189072 @default.
• W4366385236 hasConcept C2776382133 @default.
• W4366385236 hasConcept C512968161 @default.
• W4366385236 hasConcept C75473681 @default.
• W4366385236 hasConceptScore W4366385236C105281773 @default.
• W4366385236 hasConceptScore W4366385236C124681953 @default.
• W4366385236 hasConceptScore W4366385236C155672457 @default.
• W4366385236 hasConceptScore W4366385236C160434732 @default.
• W4366385236 hasConceptScore W4366385236C161790260 @default.
• W4366385236 hasConceptScore W4366385236C171250308 @default.
• W4366385236 hasConceptScore W4366385236C178790620 @default.
• W4366385236 hasConceptScore W4366385236C179104552 @default.
• W4366385236 hasConceptScore W4366385236C181258405 @default.
• W4366385236 hasConceptScore W4366385236C182606246 @default.
• W4366385236 hasConceptScore W4366385236C185592680 @default.
• W4366385236 hasConceptScore W4366385236C192562407 @default.
• W4366385236 hasConceptScore W4366385236C202189072 @default.
• W4366385236 hasConceptScore W4366385236C2776382133 @default.
• W4366385236 hasConceptScore W4366385236C512968161 @default.
• W4366385236 hasConceptScore W4366385236C75473681 @default.
• W4366385236 hasFunder F4320321001 @default.

• next