Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366439775> ?p ?o ?g. }
- W4366439775 endingPage "163596" @default.
- W4366439775 startingPage "163596" @default.
- W4366439775 abstract "Hydroxyl radical (OH) is considered the dominant reactive species in the electro-Fenton (EF) and Fered-Fenton (EF-Fere) processes for wastewater treatment. However, in chloride-rich media, this is arguable due to the obscure mechanisms for the oxidant speciation and pollutant degradation. Herein, the role of active chlorine and Fe(IV)-oxo species (FeIVO2+) as primary oxidizing agents in HClO-mediated Fered-Fenton (EF-Fere-HClO) process is discussed, along with the dependence of their contribution on the pollutant structure. HClO generated from anodic oxidation of Cl− can be consumed by added H2O2 to form singlet oxygen (1O2), which is detrimental because this species is quickly deactivated by water. The reaction between HClO and Fe2+ was proved to generate FeIVO2+, rather than OH or Cl suggested in the literature. The yield of FeIVO2+ species was proportional to the Cl− concentration and barely affected by solution pH. The long-lived HClO and FeIVO2+ can selectively react with electron-rich compounds, which occurs simultaneously to the non-selective attack of OH formed from Fenton's reaction. The FeIVO2+ and OH concentration profiles were successfully modelled. Although the accumulation of toxic chlorinated by-products from HClO-mediated oxidation might cause new environmental concerns, the toxicity of pesticide wastewater with 508 mM Cl− was halved upon EF-Fere-HClO treatment." @default.
- W4366439775 created "2023-04-21" @default.
- W4366439775 creator A5004363711 @default.
- W4366439775 creator A5006611790 @default.
- W4366439775 creator A5028941718 @default.
- W4366439775 creator A5030619988 @default.
- W4366439775 creator A5056307475 @default.
- W4366439775 creator A5068813176 @default.
- W4366439775 creator A5068952870 @default.
- W4366439775 creator A5080151139 @default.
- W4366439775 creator A5090878796 @default.
- W4366439775 date "2023-07-01" @default.
- W4366439775 modified "2023-10-12" @default.
- W4366439775 title "New insights into the mechanism of Fered-Fenton treatment of industrial wastewater with high chloride content: Role of multiple reactive species" @default.
- W4366439775 cites W1926950498 @default.
- W4366439775 cites W1984957430 @default.
- W4366439775 cites W1993174793 @default.
- W4366439775 cites W2011727188 @default.
- W4366439775 cites W2014808889 @default.
- W4366439775 cites W2017812773 @default.
- W4366439775 cites W2074196765 @default.
- W4366439775 cites W2080857416 @default.
- W4366439775 cites W2085525548 @default.
- W4366439775 cites W2087295114 @default.
- W4366439775 cites W2160363483 @default.
- W4366439775 cites W2189690206 @default.
- W4366439775 cites W2236379812 @default.
- W4366439775 cites W2301791738 @default.
- W4366439775 cites W2318792504 @default.
- W4366439775 cites W2328651177 @default.
- W4366439775 cites W2466809002 @default.
- W4366439775 cites W2777920272 @default.
- W4366439775 cites W2799483626 @default.
- W4366439775 cites W2885918363 @default.
- W4366439775 cites W2889527838 @default.
- W4366439775 cites W2902889579 @default.
- W4366439775 cites W2920930698 @default.
- W4366439775 cites W2954735260 @default.
- W4366439775 cites W3005926176 @default.
- W4366439775 cites W3006136595 @default.
- W4366439775 cites W3012072870 @default.
- W4366439775 cites W3018761455 @default.
- W4366439775 cites W3034706964 @default.
- W4366439775 cites W3038211365 @default.
- W4366439775 cites W3038876116 @default.
- W4366439775 cites W3080095772 @default.
- W4366439775 cites W3106912571 @default.
- W4366439775 cites W3125485711 @default.
- W4366439775 cites W3134329603 @default.
- W4366439775 cites W3151875622 @default.
- W4366439775 cites W3162650521 @default.
- W4366439775 cites W3184621404 @default.
- W4366439775 cites W3203201837 @default.
- W4366439775 cites W3206188628 @default.
- W4366439775 cites W3208695225 @default.
- W4366439775 cites W3209706054 @default.
- W4366439775 cites W3212960091 @default.
- W4366439775 cites W4200002079 @default.
- W4366439775 cites W4206358639 @default.
- W4366439775 cites W4221020442 @default.
- W4366439775 cites W4226188437 @default.
- W4366439775 cites W4229082321 @default.
- W4366439775 cites W4280547033 @default.
- W4366439775 cites W4281390774 @default.
- W4366439775 cites W4283163362 @default.
- W4366439775 cites W4293474888 @default.
- W4366439775 cites W4294692021 @default.
- W4366439775 doi "https://doi.org/10.1016/j.scitotenv.2023.163596" @default.
- W4366439775 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37084916" @default.
- W4366439775 hasPublicationYear "2023" @default.
- W4366439775 type Work @default.
- W4366439775 citedByCount "1" @default.
- W4366439775 countsByYear W43664397752023 @default.
- W4366439775 crossrefType "journal-article" @default.
- W4366439775 hasAuthorship W4366439775A5004363711 @default.
- W4366439775 hasAuthorship W4366439775A5006611790 @default.
- W4366439775 hasAuthorship W4366439775A5028941718 @default.
- W4366439775 hasAuthorship W4366439775A5030619988 @default.
- W4366439775 hasAuthorship W4366439775A5056307475 @default.
- W4366439775 hasAuthorship W4366439775A5068813176 @default.
- W4366439775 hasAuthorship W4366439775A5068952870 @default.
- W4366439775 hasAuthorship W4366439775A5080151139 @default.
- W4366439775 hasAuthorship W4366439775A5090878796 @default.
- W4366439775 hasConcept C107872376 @default.
- W4366439775 hasConcept C127413603 @default.
- W4366439775 hasConcept C139066938 @default.
- W4366439775 hasConcept C178790620 @default.
- W4366439775 hasConcept C179104552 @default.
- W4366439775 hasConcept C185592680 @default.
- W4366439775 hasConcept C2776778087 @default.
- W4366439775 hasConcept C2777516457 @default.
- W4366439775 hasConcept C2778695967 @default.
- W4366439775 hasConcept C2779679103 @default.
- W4366439775 hasConcept C41008148 @default.
- W4366439775 hasConcept C48349386 @default.
- W4366439775 hasConcept C505241676 @default.
- W4366439775 hasConcept C533411734 @default.
- W4366439775 hasConcept C540031477 @default.