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- W4366495401 endingPage "2675" @default.
- W4366495401 startingPage "2653" @default.
- W4366495401 abstract "Abstract Hypervalent iodine compounds have found broad application in modern organic chemistry as reagents and catalysts. Cyclic hypervalent iodine reagents based on the benziodoxole heterocyclic system have higher stability compared to their acyclic analogues, which makes possible the preparation and safe handling of the reagents with special ligands such as azido, cyano, and trifluoromethyl groups. Numerous iodine‐substituted benziodoxole derivatives have been prepared and utilized as reagents for transfer of the substituent on hypervalent iodine to organic substrate. Reactions of these reagents with organic substrates can be performed under metal‐free conditions, in the presence of transition metal catalysts, or using photocatalysts under photoirradiation conditions. In this review, we focus on the most recent synthetic applications of cyclic hypervalent iodine(III) reagents with the following ligands: N 3 , NHR, CN, CF 3 , SCF 3 , OR, OAc, ONO 2 , and C(=N 2 )CO 2 R. The review covers literature published mainly in the last 5 years." @default.
- W4366495401 created "2023-04-22" @default.
- W4366495401 creator A5037034572 @default.
- W4366495401 creator A5057096156 @default.
- W4366495401 creator A5075051195 @default.
- W4366495401 date "2023-05-03" @default.
- W4366495401 modified "2023-10-14" @default.
- W4366495401 title "Recent Progress in Synthetic Applications of Cyclic Hypervalent Iodine(III) Reagents" @default.
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