FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366603191> ?p ?o ?g. }

• W4366603191 endingPage "9856" @default.
• W4366603191 startingPage "9850" @default.
• W4366603191 abstract "Separating oxygen from air to create oxygen-enriched gas streams is a process that is significant in both industrial and medical fields. However, the prominent technologies for creating oxygen-enriched gas streams are both energy and infrastructure intensive as they use cryogenic temperatures or materials that adsorb N2 from air. The latter method is less efficient than the methods that adsorb O2 directly. Herein, we show, via a combination of gas adsorption isotherms, gas breakthrough experiments, neutron and synchrotron X-ray powder diffraction, Raman spectroscopy, and computational studies, that the metal-organic framework, Al(HCOO)3 (ALF), which is easily prepared at low cost from commodity chemicals, exhibits substantial O2 adsorption and excellent time-dependent O2/N2 selectivity in a range of 50-125 near dry ice/solvent (≈190 K) temperatures. The effective O2 adsorption with ALF at ≈190 K and ≈0.21 bar (the partial pressure of O2 in air) is ≈1.7 mmol/g, and at ice/salt temperatures (≈250 K), it is ≈0.3 mmol/g. Though the kinetics for full adsorption of O2 near 190 K are slower than at temperatures nearer 250 K, the kinetics for initial O2 adsorption are fast, suggesting that O2 separation using ALF with rapid temperature swings at ambient pressures is a potentially viable choice for low-cost air separation applications. We also present synthetic strategies for improving the kinetics of this family of compounds, namely, via Al/Fe solid solutions. To the best of our knowledge, ALF has the highest O2/N2 sorption selectivity among MOF adsorbents without open metal sites as verified by co-adsorption experiments.." @default.
• W4366603191 created "2023-04-23" @default.
• W4366603191 creator A5007648136 @default.
• W4366603191 creator A5012977814 @default.
• W4366603191 creator A5037354728 @default.
• W4366603191 creator A5037796957 @default.
• W4366603191 creator A5047629774 @default.
• W4366603191 creator A5048050496 @default.
• W4366603191 creator A5050313855 @default.
• W4366603191 creator A5056596412 @default.
• W4366603191 creator A5059783765 @default.
• W4366603191 creator A5063074878 @default.
• W4366603191 creator A5074645467 @default.
• W4366603191 creator A5075431699 @default.
• W4366603191 creator A5077586408 @default.
• W4366603191 creator A5085640753 @default.
• W4366603191 date "2023-04-21" @default.
• W4366603191 modified "2023-10-18" @default.
• W4366603191 title "Noncryogenic Air Separation Using Aluminum Formate Al(HCOO)₃ (ALF)" @default.
• W4366603191 cites W1964621160 @default.
• W4366603191 cites W1990202173 @default.
• W4366603191 cites W2020171897 @default.
• W4366603191 cites W2031085666 @default.
• W4366603191 cites W2040995650 @default.
• W4366603191 cites W2079297111 @default.
• W4366603191 cites W2084294292 @default.
• W4366603191 cites W2104595982 @default.
• W4366603191 cites W2119101083 @default.
• W4366603191 cites W2188642969 @default.
• W4366603191 cites W2325497121 @default.
• W4366603191 cites W2334071680 @default.
• W4366603191 cites W2402551245 @default.
• W4366603191 cites W2625979637 @default.
• W4366603191 cites W2943631425 @default.
• W4366603191 cites W2999807990 @default.
• W4366603191 cites W3001573773 @default.
• W4366603191 cites W3041559237 @default.
• W4366603191 cites W3165358211 @default.
• W4366603191 cites W4226227590 @default.
• W4366603191 cites W4234260370 @default.
• W4366603191 cites W4285595873 @default.
• W4366603191 cites W4291015431 @default.
• W4366603191 cites W4307930541 @default.
• W4366603191 doi "https://doi.org/10.1021/jacs.3c02100" @default.
• W4366603191 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37083432" @default.
• W4366603191 hasPublicationYear "2023" @default.
• W4366603191 type Work @default.
• W4366603191 citedByCount "8" @default.
• W4366603191 countsByYear W43666031912023 @default.
• W4366603191 crossrefType "journal-article" @default.
• W4366603191 hasAuthorship W4366603191A5007648136 @default.
• W4366603191 hasAuthorship W4366603191A5012977814 @default.
• W4366603191 hasAuthorship W4366603191A5037354728 @default.
• W4366603191 hasAuthorship W4366603191A5037796957 @default.
• W4366603191 hasAuthorship W4366603191A5047629774 @default.
• W4366603191 hasAuthorship W4366603191A5048050496 @default.
• W4366603191 hasAuthorship W4366603191A5050313855 @default.
• W4366603191 hasAuthorship W4366603191A5056596412 @default.
• W4366603191 hasAuthorship W4366603191A5059783765 @default.
• W4366603191 hasAuthorship W4366603191A5063074878 @default.
• W4366603191 hasAuthorship W4366603191A5074645467 @default.
• W4366603191 hasAuthorship W4366603191A5075431699 @default.
• W4366603191 hasAuthorship W4366603191A5077586408 @default.
• W4366603191 hasAuthorship W4366603191A5085640753 @default.
• W4366603191 hasConcept C113196181 @default.
• W4366603191 hasConcept C118792377 @default.
• W4366603191 hasConcept C121332964 @default.
• W4366603191 hasConcept C127413603 @default.
• W4366603191 hasConcept C131929883 @default.
• W4366603191 hasConcept C147789679 @default.
• W4366603191 hasConcept C148898269 @default.
• W4366603191 hasConcept C150394285 @default.
• W4366603191 hasConcept C161790260 @default.
• W4366603191 hasConcept C178790620 @default.
• W4366603191 hasConcept C179104552 @default.
• W4366603191 hasConcept C185592680 @default.
• W4366603191 hasConcept C42360764 @default.
• W4366603191 hasConcept C540031477 @default.
• W4366603191 hasConcept C58445606 @default.
• W4366603191 hasConcept C62520636 @default.
• W4366603191 hasConceptScore W4366603191C113196181 @default.
• W4366603191 hasConceptScore W4366603191C118792377 @default.
• W4366603191 hasConceptScore W4366603191C121332964 @default.
• W4366603191 hasConceptScore W4366603191C127413603 @default.
• W4366603191 hasConceptScore W4366603191C131929883 @default.
• W4366603191 hasConceptScore W4366603191C147789679 @default.
• W4366603191 hasConceptScore W4366603191C148898269 @default.
• W4366603191 hasConceptScore W4366603191C150394285 @default.
• W4366603191 hasConceptScore W4366603191C161790260 @default.
• W4366603191 hasConceptScore W4366603191C178790620 @default.
• W4366603191 hasConceptScore W4366603191C179104552 @default.
• W4366603191 hasConceptScore W4366603191C185592680 @default.
• W4366603191 hasConceptScore W4366603191C42360764 @default.
• W4366603191 hasConceptScore W4366603191C540031477 @default.
• W4366603191 hasConceptScore W4366603191C58445606 @default.
• W4366603191 hasConceptScore W4366603191C62520636 @default.
• W4366603191 hasFunder F4320313829 @default.
• W4366603191 hasFunder F4320314062 @default.

• next