Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366722002> ?p ?o ?g. }
- W4366722002 abstract "Herein, a copper(I)-catalyzed asymmetric conjugate addition/protonation with selenols and α-substituted α,β-unsaturated thioamides is disclosed, which affords a series of chiral selenides in high to excellent enantioselectivity. As for both selenols and α-substituted α,β-unsaturated thioamides, the reaction enjoys broad substrate scopes. The present catalytic system is also successfully applied to asymmetric selenation of β-substituted α,β-unsaturated thioamides. A [Cu-(R,RP )-TANIAPHOS]-SePh species is characterized by its 77 Se NMR spectra, which gives a chemical shift at δ 462 ppm. Moreover, a {[Cu-(R)-TOL-BINAP]-SePh}2 species is characterized by X-ray analysis, which confirms the formation of Cu-Se bond in the reaction. Finally, the transformations of the thioamide group to amine and thioester are demonstrated to be straightforward." @default.
- W4366722002 created "2023-04-24" @default.
- W4366722002 creator A5025530714 @default.
- W4366722002 creator A5027019343 @default.
- W4366722002 creator A5079570262 @default.
- W4366722002 date "2023-05-08" @default.
- W4366722002 modified "2023-10-12" @default.
- W4366722002 title "Copper(I)‐Catalyzed Conjugate Addition/Enantioselective Protonation with Selenols and α‐Substituted α,β‐Unsaturated Thioamides" @default.
- W4366722002 cites W1971317846 @default.
- W4366722002 cites W1972880477 @default.
- W4366722002 cites W1984470054 @default.
- W4366722002 cites W1995085653 @default.
- W4366722002 cites W1997386639 @default.
- W4366722002 cites W2017339707 @default.
- W4366722002 cites W2022590696 @default.
- W4366722002 cites W2027247359 @default.
- W4366722002 cites W2035528714 @default.
- W4366722002 cites W2040549881 @default.
- W4366722002 cites W2056575495 @default.
- W4366722002 cites W2069848952 @default.
- W4366722002 cites W2074357306 @default.
- W4366722002 cites W2078711959 @default.
- W4366722002 cites W2079680604 @default.
- W4366722002 cites W2088032007 @default.
- W4366722002 cites W2103363626 @default.
- W4366722002 cites W2126421555 @default.
- W4366722002 cites W2145337402 @default.
- W4366722002 cites W2150456812 @default.
- W4366722002 cites W2163452430 @default.
- W4366722002 cites W2178118169 @default.
- W4366722002 cites W2313688287 @default.
- W4366722002 cites W2319106218 @default.
- W4366722002 cites W2324049150 @default.
- W4366722002 cites W2332413183 @default.
- W4366722002 cites W2438431483 @default.
- W4366722002 cites W2473486504 @default.
- W4366722002 cites W2763793342 @default.
- W4366722002 cites W2797421292 @default.
- W4366722002 cites W2811513022 @default.
- W4366722002 cites W2883416535 @default.
- W4366722002 cites W2913697671 @default.
- W4366722002 cites W2949077609 @default.
- W4366722002 cites W2949563976 @default.
- W4366722002 cites W2950928052 @default.
- W4366722002 cites W3012423995 @default.
- W4366722002 cites W3019844709 @default.
- W4366722002 cites W3033596352 @default.
- W4366722002 cites W3092285572 @default.
- W4366722002 cites W3116570459 @default.
- W4366722002 cites W3134782775 @default.
- W4366722002 cites W3213880006 @default.
- W4366722002 cites W3214786508 @default.
- W4366722002 cites W4220836040 @default.
- W4366722002 cites W4232392260 @default.
- W4366722002 cites W4293056516 @default.
- W4366722002 cites W4297094434 @default.
- W4366722002 doi "https://doi.org/10.1002/anie.202301422" @default.
- W4366722002 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37085464" @default.
- W4366722002 hasPublicationYear "2023" @default.
- W4366722002 type Work @default.
- W4366722002 citedByCount "0" @default.
- W4366722002 crossrefType "journal-article" @default.
- W4366722002 hasAuthorship W4366722002A5025530714 @default.
- W4366722002 hasAuthorship W4366722002A5027019343 @default.
- W4366722002 hasAuthorship W4366722002A5079570262 @default.
- W4366722002 hasConcept C131779359 @default.
- W4366722002 hasConcept C134306372 @default.
- W4366722002 hasConcept C145148216 @default.
- W4366722002 hasConcept C146686406 @default.
- W4366722002 hasConcept C155647269 @default.
- W4366722002 hasConcept C161790260 @default.
- W4366722002 hasConcept C178790620 @default.
- W4366722002 hasConcept C185592680 @default.
- W4366722002 hasConcept C197336794 @default.
- W4366722002 hasConcept C21951064 @default.
- W4366722002 hasConcept C2777650178 @default.
- W4366722002 hasConcept C30095370 @default.
- W4366722002 hasConcept C33923547 @default.
- W4366722002 hasConcept C544778455 @default.
- W4366722002 hasConceptScore W4366722002C131779359 @default.
- W4366722002 hasConceptScore W4366722002C134306372 @default.
- W4366722002 hasConceptScore W4366722002C145148216 @default.
- W4366722002 hasConceptScore W4366722002C146686406 @default.
- W4366722002 hasConceptScore W4366722002C155647269 @default.
- W4366722002 hasConceptScore W4366722002C161790260 @default.
- W4366722002 hasConceptScore W4366722002C178790620 @default.
- W4366722002 hasConceptScore W4366722002C185592680 @default.
- W4366722002 hasConceptScore W4366722002C197336794 @default.
- W4366722002 hasConceptScore W4366722002C21951064 @default.
- W4366722002 hasConceptScore W4366722002C2777650178 @default.
- W4366722002 hasConceptScore W4366722002C30095370 @default.
- W4366722002 hasConceptScore W4366722002C33923547 @default.
- W4366722002 hasConceptScore W4366722002C544778455 @default.
- W4366722002 hasIssue "24" @default.
- W4366722002 hasLocation W43667220021 @default.
- W4366722002 hasLocation W43667220022 @default.
- W4366722002 hasOpenAccess W4366722002 @default.
- W4366722002 hasPrimaryLocation W43667220021 @default.
- W4366722002 hasRelatedWork W1602631394 @default.
- W4366722002 hasRelatedWork W1967077784 @default.