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- W4366722148 abstract "The impact of NMR on paramagnetic molecules and materials, however, is hampered by the very same enhanced paramagnetic shifts, shift anisotropies, and relaxation rates. In the presence of large paramagnetic effects, 1D NMR experiments provide the most straightforward and sensitive fingerprint to probe the surrounding of a paramagnetic center. In this chapter, the authors survey the experimental 2D NMR methods that have either been used on or are applicable to paramagnetic systems. These comprise many NMR pulse sequences that have been designed for diamagnetic systems, including small- to medium-sized molecules in solution, large biomolecules in solution, solid materials, and biosolids. They discuss the modifications required in order to apply these methods to paramagnetic systems, and additionally present the tailored schemes, designed specifically to evaluate quantitatively paramagnetic effects." @default.
- W4366722148 created "2023-04-24" @default.
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- W4366722148 date "2023-04-14" @default.
- W4366722148 modified "2023-10-02" @default.
- W4366722148 title "Multidimensional Methods and Paramagnetic <scp>NMR</scp>" @default.
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- W4366722148 doi "https://doi.org/10.1002/9781119806721.ch14" @default.
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