Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366742307> ?p ?o ?g. }
- W4366742307 abstract "Photo-driven CH4 conversion to multi-carbon products and H2 is attractive but challenging, and the development of efficient catalytic systems is critical. Herein, we construct a solar-energy-driven redox cycle for combining CH4 conversion and H2 production using iron ions. A photo-driven iron-induced reaction system was developed, which is efficient at selective coupling of CH4 as well as conversion of benzene and cyclohexane under mild conditions. For CH4 conversion, 94 % C2 selectivity and a C2 H6 formation rate of 8.4 μmol h-1 is achieved. Mechanistic studies reveal that CH4 coupling is induced by hydroxyl radical, which is generated by photo-driven intermolecular charge migration of an Fe3+ complex. The delicate coordination structure of the [Fe(H2 O)5 OH]2+ complex ensures selective C-H bond activation and C-C coupling of CH4 . The produced Fe2+ can be used to reduce the potential for electrolytic H2 production, and then turns back into Fe3+ , forming an energy-saving and sustainable recyclable system." @default.
- W4366742307 created "2023-04-24" @default.
- W4366742307 creator A5006005295 @default.
- W4366742307 creator A5009066967 @default.
- W4366742307 creator A5015510835 @default.
- W4366742307 creator A5017266806 @default.
- W4366742307 creator A5026338239 @default.
- W4366742307 creator A5031458979 @default.
- W4366742307 creator A5039135526 @default.
- W4366742307 creator A5055643899 @default.
- W4366742307 creator A5065592637 @default.
- W4366742307 creator A5075404687 @default.
- W4366742307 creator A5084275324 @default.
- W4366742307 date "2023-05-09" @default.
- W4366742307 modified "2023-10-17" @default.
- W4366742307 title "Photo‐Driven Iron‐Induced Non‐Oxidative Coupling of Methane to Ethane" @default.
- W4366742307 cites W1974197538 @default.
- W4366742307 cites W2015344888 @default.
- W4366742307 cites W2058860627 @default.
- W4366742307 cites W2106094711 @default.
- W4366742307 cites W2119319723 @default.
- W4366742307 cites W2168987628 @default.
- W4366742307 cites W2273685899 @default.
- W4366742307 cites W2552432353 @default.
- W4366742307 cites W2568038773 @default.
- W4366742307 cites W2593124874 @default.
- W4366742307 cites W2611158094 @default.
- W4366742307 cites W2611302578 @default.
- W4366742307 cites W2779985101 @default.
- W4366742307 cites W2887887261 @default.
- W4366742307 cites W2928083827 @default.
- W4366742307 cites W2947186655 @default.
- W4366742307 cites W2962139611 @default.
- W4366742307 cites W2995827724 @default.
- W4366742307 cites W3025783110 @default.
- W4366742307 cites W3094914438 @default.
- W4366742307 cites W3111751935 @default.
- W4366742307 cites W3118233036 @default.
- W4366742307 cites W3122792947 @default.
- W4366742307 cites W3125237687 @default.
- W4366742307 cites W3135891482 @default.
- W4366742307 cites W3186875713 @default.
- W4366742307 cites W3186924850 @default.
- W4366742307 cites W4225121728 @default.
- W4366742307 cites W4251586667 @default.
- W4366742307 cites W4280648086 @default.
- W4366742307 cites W4283367240 @default.
- W4366742307 cites W4297996559 @default.
- W4366742307 cites W4308443578 @default.
- W4366742307 cites W4378418253 @default.
- W4366742307 doi "https://doi.org/10.1002/anie.202303405" @default.
- W4366742307 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37085959" @default.
- W4366742307 hasPublicationYear "2023" @default.
- W4366742307 type Work @default.
- W4366742307 citedByCount "1" @default.
- W4366742307 countsByYear W43667423072023 @default.
- W4366742307 crossrefType "journal-article" @default.
- W4366742307 hasAuthorship W4366742307A5006005295 @default.
- W4366742307 hasAuthorship W4366742307A5009066967 @default.
- W4366742307 hasAuthorship W4366742307A5015510835 @default.
- W4366742307 hasAuthorship W4366742307A5017266806 @default.
- W4366742307 hasAuthorship W4366742307A5026338239 @default.
- W4366742307 hasAuthorship W4366742307A5031458979 @default.
- W4366742307 hasAuthorship W4366742307A5039135526 @default.
- W4366742307 hasAuthorship W4366742307A5055643899 @default.
- W4366742307 hasAuthorship W4366742307A5065592637 @default.
- W4366742307 hasAuthorship W4366742307A5075404687 @default.
- W4366742307 hasAuthorship W4366742307A5084275324 @default.
- W4366742307 hasConcept C118792377 @default.
- W4366742307 hasConcept C131584629 @default.
- W4366742307 hasConcept C161790260 @default.
- W4366742307 hasConcept C166950319 @default.
- W4366742307 hasConcept C178790620 @default.
- W4366742307 hasConcept C179104552 @default.
- W4366742307 hasConcept C185592680 @default.
- W4366742307 hasConcept C191897082 @default.
- W4366742307 hasConcept C192562407 @default.
- W4366742307 hasConcept C2778237882 @default.
- W4366742307 hasConcept C32909587 @default.
- W4366742307 hasConcept C516920438 @default.
- W4366742307 hasConcept C55904794 @default.
- W4366742307 hasConcept C75473681 @default.
- W4366742307 hasConcept C83155894 @default.
- W4366742307 hasConceptScore W4366742307C118792377 @default.
- W4366742307 hasConceptScore W4366742307C131584629 @default.
- W4366742307 hasConceptScore W4366742307C161790260 @default.
- W4366742307 hasConceptScore W4366742307C166950319 @default.
- W4366742307 hasConceptScore W4366742307C178790620 @default.
- W4366742307 hasConceptScore W4366742307C179104552 @default.
- W4366742307 hasConceptScore W4366742307C185592680 @default.
- W4366742307 hasConceptScore W4366742307C191897082 @default.
- W4366742307 hasConceptScore W4366742307C192562407 @default.
- W4366742307 hasConceptScore W4366742307C2778237882 @default.
- W4366742307 hasConceptScore W4366742307C32909587 @default.
- W4366742307 hasConceptScore W4366742307C516920438 @default.
- W4366742307 hasConceptScore W4366742307C55904794 @default.
- W4366742307 hasConceptScore W4366742307C75473681 @default.
- W4366742307 hasConceptScore W4366742307C83155894 @default.
- W4366742307 hasFunder F4320321001 @default.
- W4366742307 hasFunder F4320335787 @default.