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• W4366976219 abstract "Abstract A NaH‐promoted domino reaction between azadiene bearing an indene moiety with Nazarov reagent was developed. A variety of spiro[4.5]decane derivatives were obtained via [4+2] cycloaddition with good yields and high diastereoselectivity. The domino strategy benefited from mild reaction conditions and very broad substrate scope. Furthermore, a gram‐scale experiment and a transformation of the product were carried out. Lastly, density functional theory (DFT) calculations have been performed to verify the proposed reaction mechanism and analyze the observed diastereoselectivity." @default.
• W4366976219 created "2023-04-27" @default.
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• W4366976219 date "2023-05-09" @default.
• W4366976219 modified "2023-10-17" @default.
• W4366976219 title "Construction of Spiro[4.5]decanes via Annulations of Azadienes with Nazarov Reagent and DFT Studies" @default.
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• W4366976219 doi "https://doi.org/10.1002/ajoc.202300152" @default.
• W4366976219 hasPublicationYear "2023" @default.
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