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- W4366976228 abstract "Abstract An aerobic coupling of benzhydryl phosphonium salts with simple alkenes for accessing trisubstituted olefins is developed under metal‐free, catalyst‐free, and additive‐free conditions. New C( sp 3 )−C( sp 2 ) bond is constructed via the C−P and C−H bond functionalization by synergistically using O 2 as a “green” oxidant and DMSO as a promoter. The method also distinguishes itself by its broad substrate scope and synthetic potential. Particularly, the use of 1,3,5‐trimethoxybenzene fragment in the resulting products as a carbon‐based leaving group for further transformations is proved to be feasible." @default.
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- W4366976228 date "2023-05-31" @default.
- W4366976228 modified "2023-10-15" @default.
- W4366976228 title "Aerobic Coupling of Organophosphonium Salts with Alkenes: Catalyst‐Free C(<i>sp</i><sup>3</sup>)−C(<i>sp</i><sup>2</sup>) Bond Formation" @default.
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- W4366976228 doi "https://doi.org/10.1002/adsc.202300259" @default.
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