Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366985504> ?p ?o ?g. }
- W4366985504 abstract "Abstract Besides a stable phase, shape‐memory polymers require an additional switchable moiety. In addition to thermal transitions and supramolecular interactions, these units can also be based on covalent bonds. Herein, the use of the reversible thiol‐ene reaction as reversible cross‐linker for the design of shape‐memory polymers is demonstrated. A facile route to polymer networks with a thiol‐ene acceptor and a comonomer (butyl methacrylate or 2‐ethylhexyl methacrylate) cross‐linked by dithiols is introduced. The thermal and mechanical properties of the resulting polymers are characterized in detail. Hereby, the polymers feature excellent shape‐memory behavior with fixity and recovery rates above 90%. This study shows that the thiol‐ene cross‐linker can function as both, the stable and the switchable structural moiety rendering the usage of a covalent cross‐linker unnecessary. This partial reversibility can also be proven by temperature‐depending Raman spectroscopy." @default.
- W4366985504 created "2023-04-27" @default.
- W4366985504 creator A5004949170 @default.
- W4366985504 creator A5005585069 @default.
- W4366985504 creator A5005918382 @default.
- W4366985504 creator A5019499026 @default.
- W4366985504 creator A5040244255 @default.
- W4366985504 creator A5047546319 @default.
- W4366985504 creator A5055566096 @default.
- W4366985504 date "2023-04-25" @default.
- W4366985504 modified "2023-10-18" @default.
- W4366985504 title "Thiol‐ene Reaction as Reversible Covalent Bond for the Design of Shape‐Memory Polymers" @default.
- W4366985504 cites W1963036046 @default.
- W4366985504 cites W1975508278 @default.
- W4366985504 cites W1987378812 @default.
- W4366985504 cites W1995645236 @default.
- W4366985504 cites W2012016930 @default.
- W4366985504 cites W2017569023 @default.
- W4366985504 cites W2017741151 @default.
- W4366985504 cites W2024129669 @default.
- W4366985504 cites W2043117507 @default.
- W4366985504 cites W2062333922 @default.
- W4366985504 cites W2079296603 @default.
- W4366985504 cites W2085682576 @default.
- W4366985504 cites W2100237453 @default.
- W4366985504 cites W2125276562 @default.
- W4366985504 cites W2210121493 @default.
- W4366985504 cites W2216421858 @default.
- W4366985504 cites W2528375074 @default.
- W4366985504 cites W2535849056 @default.
- W4366985504 cites W2580051194 @default.
- W4366985504 cites W2618036353 @default.
- W4366985504 cites W2660587980 @default.
- W4366985504 cites W2748540641 @default.
- W4366985504 cites W2891703710 @default.
- W4366985504 cites W2909091922 @default.
- W4366985504 cites W2909857791 @default.
- W4366985504 cites W2921650525 @default.
- W4366985504 cites W2976130428 @default.
- W4366985504 cites W2980513544 @default.
- W4366985504 cites W2983077176 @default.
- W4366985504 cites W2983629096 @default.
- W4366985504 cites W2990218975 @default.
- W4366985504 cites W2998739015 @default.
- W4366985504 cites W3005250601 @default.
- W4366985504 cites W3033449785 @default.
- W4366985504 cites W3045793501 @default.
- W4366985504 cites W3113107960 @default.
- W4366985504 cites W3118760055 @default.
- W4366985504 cites W3142999281 @default.
- W4366985504 cites W3159382127 @default.
- W4366985504 cites W3167470777 @default.
- W4366985504 cites W3184787083 @default.
- W4366985504 cites W3187552764 @default.
- W4366985504 cites W3193651192 @default.
- W4366985504 cites W4220930260 @default.
- W4366985504 cites W4294702181 @default.
- W4366985504 cites W4312589911 @default.
- W4366985504 doi "https://doi.org/10.1002/mame.202300002" @default.
- W4366985504 hasPublicationYear "2023" @default.
- W4366985504 type Work @default.
- W4366985504 citedByCount "0" @default.
- W4366985504 crossrefType "journal-article" @default.
- W4366985504 hasAuthorship W4366985504A5004949170 @default.
- W4366985504 hasAuthorship W4366985504A5005585069 @default.
- W4366985504 hasAuthorship W4366985504A5005918382 @default.
- W4366985504 hasAuthorship W4366985504A5019499026 @default.
- W4366985504 hasAuthorship W4366985504A5040244255 @default.
- W4366985504 hasAuthorship W4366985504A5047546319 @default.
- W4366985504 hasAuthorship W4366985504A5055566096 @default.
- W4366985504 hasBestOaLocation W43669855041 @default.
- W4366985504 hasConcept C130929614 @default.
- W4366985504 hasConcept C132050475 @default.
- W4366985504 hasConcept C159985019 @default.
- W4366985504 hasConcept C178790620 @default.
- W4366985504 hasConcept C180577832 @default.
- W4366985504 hasConcept C185592680 @default.
- W4366985504 hasConcept C188027245 @default.
- W4366985504 hasConcept C192562407 @default.
- W4366985504 hasConcept C2776568683 @default.
- W4366985504 hasConcept C27777614 @default.
- W4366985504 hasConcept C32909587 @default.
- W4366985504 hasConcept C44228677 @default.
- W4366985504 hasConcept C521977710 @default.
- W4366985504 hasConcept C93275456 @default.
- W4366985504 hasConceptScore W4366985504C130929614 @default.
- W4366985504 hasConceptScore W4366985504C132050475 @default.
- W4366985504 hasConceptScore W4366985504C159985019 @default.
- W4366985504 hasConceptScore W4366985504C178790620 @default.
- W4366985504 hasConceptScore W4366985504C180577832 @default.
- W4366985504 hasConceptScore W4366985504C185592680 @default.
- W4366985504 hasConceptScore W4366985504C188027245 @default.
- W4366985504 hasConceptScore W4366985504C192562407 @default.
- W4366985504 hasConceptScore W4366985504C2776568683 @default.
- W4366985504 hasConceptScore W4366985504C27777614 @default.
- W4366985504 hasConceptScore W4366985504C32909587 @default.
- W4366985504 hasConceptScore W4366985504C44228677 @default.
- W4366985504 hasConceptScore W4366985504C521977710 @default.
- W4366985504 hasConceptScore W4366985504C93275456 @default.
- W4366985504 hasFunder F4320320879 @default.