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- W4366985910 abstract "The first catalytic asymmetric cascade Heck-alkylation reaction of NH2-unprotected amino acid esters with N-(2-iodophenyl)allenamides is reported in this work. Under the promotion of a combining catalytic system comprising a chiral aldehyde, a chiral palladium complex, and the Lewis acid ZnCl2, the title reaction takes place smoothly, giving optically active α-alkyl tryptophan derivatives in moderate to good yields and excellent enantioselectivities. The target products can be converted into other structurally complex chiral indoles without the loss of enantioselectivities." @default.
- W4366985910 created "2023-04-27" @default.
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- W4366985910 date "2023-04-25" @default.
- W4366985910 modified "2023-10-14" @default.
- W4366985910 title "Chiral Aldehyde–Palladium Catalysis Enables Asymmetric Synthesis of α-Alkyl Tryptophans via Cascade Heck-Alkylation Reaction" @default.
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- W4366985910 doi "https://doi.org/10.1021/acs.orglett.3c01119" @default.
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