Matches in SemOpenAlex for { <https://semopenalex.org/work/W4366987279> ?p ?o ?g. }
- W4366987279 abstract "The reaction between N ‐(benzylidene)benzylamines ( p‐ RC 6 H 4 CH=NCH 2 C 6 H 5 ; R = Cl, H, NO 2 , F, OMe), [RuCl 2 ( η 6 ‐ p‐ cymene)] 2 and potassium acetate has cleanly furnished the corresponding cycloruthenated complexes C1–C5 . The process is completely regioselective, with the formation in all cases of the endo ‐derivative, independently of the substituent of the aromatic ring. The five‐membered endo ‐metallacycles C6 and C7 can also be obtained from the enantiopure imines ( R C )‐ p‐ RC 6 H 4 CH=NCHMeC 10 H 7 (R = Cl, H, respectively) working under similar conditions. The crystal structures of the seven metallated compounds have been determined by X‐ray diffraction. These complexes are active as catalyst precursors for the reduction of acetophenone and benzophenone by transfer hydrogenation. An enantiomeric excess of up to 77% at room temperature has been obtained with the complex C7 in the reduction of acetophenone." @default.
- W4366987279 created "2023-04-27" @default.
- W4366987279 creator A5017506922 @default.
- W4366987279 creator A5020221698 @default.
- W4366987279 creator A5032769856 @default.
- W4366987279 creator A5054003271 @default.
- W4366987279 creator A5056975757 @default.
- W4366987279 creator A5061420118 @default.
- W4366987279 creator A5074654155 @default.
- W4366987279 creator A5081597067 @default.
- W4366987279 creator A5089714850 @default.
- W4366987279 date "2023-05-05" @default.
- W4366987279 modified "2023-10-18" @default.
- W4366987279 title "Regioselective cycloruthenation of <i>N</i>‐(benzylidene)benzylamines: Enantiopure catalysts for transfer hydrogenation" @default.
- W4366987279 cites W120728943 @default.
- W4366987279 cites W1902438951 @default.
- W4366987279 cites W1966255413 @default.
- W4366987279 cites W1973531385 @default.
- W4366987279 cites W1977481419 @default.
- W4366987279 cites W1979860270 @default.
- W4366987279 cites W1988305061 @default.
- W4366987279 cites W1994374884 @default.
- W4366987279 cites W1994628146 @default.
- W4366987279 cites W1996972417 @default.
- W4366987279 cites W2014512699 @default.
- W4366987279 cites W2025253673 @default.
- W4366987279 cites W2040932614 @default.
- W4366987279 cites W2043935388 @default.
- W4366987279 cites W2048642635 @default.
- W4366987279 cites W2051023614 @default.
- W4366987279 cites W2051162951 @default.
- W4366987279 cites W2054713137 @default.
- W4366987279 cites W2057086900 @default.
- W4366987279 cites W2068589900 @default.
- W4366987279 cites W2070310556 @default.
- W4366987279 cites W2075342746 @default.
- W4366987279 cites W2088185150 @default.
- W4366987279 cites W2092620903 @default.
- W4366987279 cites W2111225834 @default.
- W4366987279 cites W2121392843 @default.
- W4366987279 cites W2137260662 @default.
- W4366987279 cites W2152127246 @default.
- W4366987279 cites W2174801917 @default.
- W4366987279 cites W2302054269 @default.
- W4366987279 cites W2321928492 @default.
- W4366987279 cites W2372709 @default.
- W4366987279 cites W2558538308 @default.
- W4366987279 cites W285527989 @default.
- W4366987279 cites W2973975365 @default.
- W4366987279 cites W3177428175 @default.
- W4366987279 cites W4213195811 @default.
- W4366987279 cites W4253609458 @default.
- W4366987279 doi "https://doi.org/10.1002/aoc.7115" @default.
- W4366987279 hasPublicationYear "2023" @default.
- W4366987279 type Work @default.
- W4366987279 citedByCount "0" @default.
- W4366987279 crossrefType "journal-article" @default.
- W4366987279 hasAuthorship W4366987279A5017506922 @default.
- W4366987279 hasAuthorship W4366987279A5020221698 @default.
- W4366987279 hasAuthorship W4366987279A5032769856 @default.
- W4366987279 hasAuthorship W4366987279A5054003271 @default.
- W4366987279 hasAuthorship W4366987279A5056975757 @default.
- W4366987279 hasAuthorship W4366987279A5061420118 @default.
- W4366987279 hasAuthorship W4366987279A5074654155 @default.
- W4366987279 hasAuthorship W4366987279A5081597067 @default.
- W4366987279 hasAuthorship W4366987279A5089714850 @default.
- W4366987279 hasBestOaLocation W43669872791 @default.
- W4366987279 hasConcept C146686406 @default.
- W4366987279 hasConcept C155647269 @default.
- W4366987279 hasConcept C161790260 @default.
- W4366987279 hasConcept C178790620 @default.
- W4366987279 hasConcept C185592680 @default.
- W4366987279 hasConcept C2775888733 @default.
- W4366987279 hasConcept C2776715866 @default.
- W4366987279 hasConcept C2778279444 @default.
- W4366987279 hasConcept C2778689049 @default.
- W4366987279 hasConcept C2780378348 @default.
- W4366987279 hasConcept C3141732 @default.
- W4366987279 hasConcept C486523 @default.
- W4366987279 hasConcept C555196967 @default.
- W4366987279 hasConcept C59759590 @default.
- W4366987279 hasConcept C71240020 @default.
- W4366987279 hasConcept C93237805 @default.
- W4366987279 hasConceptScore W4366987279C146686406 @default.
- W4366987279 hasConceptScore W4366987279C155647269 @default.
- W4366987279 hasConceptScore W4366987279C161790260 @default.
- W4366987279 hasConceptScore W4366987279C178790620 @default.
- W4366987279 hasConceptScore W4366987279C185592680 @default.
- W4366987279 hasConceptScore W4366987279C2775888733 @default.
- W4366987279 hasConceptScore W4366987279C2776715866 @default.
- W4366987279 hasConceptScore W4366987279C2778279444 @default.
- W4366987279 hasConceptScore W4366987279C2778689049 @default.
- W4366987279 hasConceptScore W4366987279C2780378348 @default.
- W4366987279 hasConceptScore W4366987279C3141732 @default.
- W4366987279 hasConceptScore W4366987279C486523 @default.
- W4366987279 hasConceptScore W4366987279C555196967 @default.
- W4366987279 hasConceptScore W4366987279C59759590 @default.
- W4366987279 hasConceptScore W4366987279C71240020 @default.
- W4366987279 hasConceptScore W4366987279C93237805 @default.
- W4366987279 hasFunder F4320322930 @default.