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• W4366991673 startingPage "3089" @default.
• W4366991673 abstract "Herein, we present a simplified reaction protocol for the dearomatization of bicyclic azaarenes via photochemical cycloaddition with alkenes using an Ir(III) photosensitizer, trifluoroacetic acid (TFA), dichloroethane, and a blue light-emitting diode. An efficient protonation of azaarenes with TFA enhances the reactivity of triplet azaarene toward olefins, enabling the photocycloaddition under aerobic conditions. The protocol applies to a broad range of substrates. Control experiments indicate a strong correlation between the degree of protonation of azaarene and the product yield." @default.
• W4366991673 created "2023-04-27" @default.
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• W4366991673 date "2023-04-25" @default.
• W4366991673 modified "2023-10-17" @default.
• W4366991673 title "Brønsted Acid-Promoted Intermolecular Dearomative Photocycloaddition of Bicyclic Azaarenes with Olefins under Aerobic Conditions" @default.
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• W4366991673 doi "https://doi.org/10.1021/acs.orglett.3c00917" @default.
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