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- W4366992309 abstract "We report for the first time a novel process to fabricate superparamagnetic polyvinylidene fluoride (PVDF) composite nanofiber films by electrospinning process suitable for enhanced oil sludge removal applications. Organic coating and inorganic capping of superparamagnetic magnetic nanoparticles (MNPs) are used to enhance the dispersibility of nanoparticles in the polymer solution using carboxymethyl cellulose and manganese oxide (MnOx), respectively. The prepared fibers were hydrophobic with a water contact angle (WCA) between 119 and 128°. The addition of MNPs reduced the fiber diameter from 164 to 78 nm. Oil adsorption studies were carried out using oils with different carbon lengths and densities. An increase in sorption capacity with an increase in magnetic nanoparticle loading in PVDF is observed. The highest sorption capacity of 38 g/g for oleic acid was observed with 10 wt% loading of particles, due to a large number of pores within the fiber. Only a very slight reduction in oil sorption capacity was observed after regeneration for five cycles due to the superparamagnetic nature of MNPs, which shows the immense prospect of the prepared composite for oil sludge removal. Also, the new procedure overcomes the problems of non-uniform anchoring on fibers, agglomeration of particles, and multiple steps involved in the fabrication process." @default.
- W4366992309 created "2023-04-27" @default.
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- W4366992309 date "2023-08-01" @default.
- W4366992309 modified "2023-10-04" @default.
- W4366992309 title "Electrospun superparamagnetic fibrous composite nanofiber films for enhanced oil spill recovery: Effect of capping and magnetic nanoparticle loading on oil sorption efficiency" @default.
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- W4366992309 doi "https://doi.org/10.1016/j.compositesa.2023.107591" @default.
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