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- W4366997959 endingPage "1855" @default.
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- W4366997959 abstract "Abstract Due to the wide range of compositional possibilities in the high-entropy alloy (HEA) field, empirical models and the CALPHAD method have been implemented to efficiently design HEAs. Although most design strategies have been tested on as-cast alloys, their validation for thermal sprayed HEA coatings is lacking. In this work, empirical models and the CALPHAD method under equilibrium and non-equilibrium conditions are assessed for phase prediction in five HEAs in the as-cast, laser clad and thermal sprayed conditions. High-velocity oxygen fuel coatings were prepared for these five HEAs, and their phases were identified by the x-ray diffraction analysis. These processes, even though their cooling rates vary significantly, show similar phase formation as indicated by a literature review and the current experimental study. The CALPHAD equilibrium calculation predicted most of the phases at specified temperatures. Furthermore, the CALPHAD-based non-equilibrium simulations correctly predicted the major phases present in the HEA coatings. The empirical models also show good prediction capability, but the intermetallic sigma phase is problematic for the parameter-based models. Therefore, the CALPHAD method can be used to efficiently design and develop HEAs prepared under conditions that encompass rapid cooling, such as occurring during thermal spray processes." @default.
- W4366997959 created "2023-04-27" @default.
- W4366997959 creator A5001546124 @default.
- W4366997959 creator A5008170942 @default.
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- W4366997959 creator A5048306434 @default.
- W4366997959 creator A5070499439 @default.
- W4366997959 creator A5074758025 @default.
- W4366997959 date "2023-04-25" @default.
- W4366997959 modified "2023-09-26" @default.
- W4366997959 title "Empirical and Computational-Based Phase Predictions of Thermal Sprayed High-Entropy Alloys" @default.
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- W4366997959 doi "https://doi.org/10.1007/s11666-023-01586-2" @default.
- W4366997959 hasPublicationYear "2023" @default.