FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367011894> ?p ?o ?g. }

• W4367011894 endingPage "6542" @default.
• W4367011894 startingPage "6536" @default.
• W4367011894 abstract "An innovative mineral carbonation method was developed to synthesize iron(II) carbonate (FeCO3) by cation complexation using 2,2'-bipyridine as ligand. First, complexes of iron(II) and different ligands were theoretically analyzed and discounted in terms of their temperature and pH-dependent stabilities, iron-ligand interactions, possible by-products and difficulty of analysis, choosing 2,2'-bipyridine as the most suitable ligand. Then, the Job plot was used to verify the complex formula. The stability of [Fe(bipy)3]2+ at pH 1-12 was further monitored for 7 days using UV-Vis and IR spectroscopy. Good stability was observed between pH 3 and 8, decreasing within pH 9-12 where the carbonation reaction occurs. Finally, the reaction between Na2CO3 and [Fe(bipy)3]2+ was performed at 21, 60, and 80 °C and pH 9-12. The total inorganic carbon measured after 2 h shows that the best carbonate conversion (50%) occurred at 80 °C and pH 11, being the most suitable conditions for carbon sequestration. SEM-EDS and XRD were used to examine the effect of synthesis parameters on the morphology and composition of FeCO3. The FeCO3 particle size increased from 10 μm at 21 °C to 26 and 170 μm at 60 and 80 °C respectively with no pH dependence. In addition, EDS analysis supported the carbonate identity, whose amorphous nature was confirmed by XRD. These results would help prevent the iron hydroxide precipitation problem during mineral carbonation using iron-rich silicates. These results are promising for its application as a carbon sequestration method with a CO2 uptake of around 50% obtaining Fe-rich carbonate." @default.
• W4367011894 created "2023-04-27" @default.
• W4367011894 creator A5005234987 @default.
• W4367011894 creator A5011576885 @default.
• W4367011894 creator A5041779175 @default.
• W4367011894 creator A5076200264 @default.
• W4367011894 date "2023-01-01" @default.
• W4367011894 modified "2023-10-16" @default.
• W4367011894 title "Carbon dioxide sequestration by mineral carbonation <i>via</i> iron complexation using bipyridine chelating ligands" @default.
• W4367011894 cites W1277067537 @default.
• W4367011894 cites W1786319299 @default.
• W4367011894 cites W180326383 @default.
• W4367011894 cites W1964537205 @default.
• W4367011894 cites W1974444716 @default.
• W4367011894 cites W1976991511 @default.
• W4367011894 cites W1978634537 @default.
• W4367011894 cites W1982530719 @default.
• W4367011894 cites W1999909316 @default.
• W4367011894 cites W2006736361 @default.
• W4367011894 cites W2019413248 @default.
• W4367011894 cites W2020942931 @default.
• W4367011894 cites W2031778798 @default.
• W4367011894 cites W2033986829 @default.
• W4367011894 cites W2041132372 @default.
• W4367011894 cites W2071576644 @default.
• W4367011894 cites W2072904866 @default.
• W4367011894 cites W2113161125 @default.
• W4367011894 cites W2119460838 @default.
• W4367011894 cites W2151003442 @default.
• W4367011894 cites W2160747368 @default.
• W4367011894 cites W2314316515 @default.
• W4367011894 cites W2323453729 @default.
• W4367011894 cites W2335060932 @default.
• W4367011894 cites W2402454737 @default.
• W4367011894 cites W2415783760 @default.
• W4367011894 cites W2537094838 @default.
• W4367011894 cites W2543899860 @default.
• W4367011894 cites W2793784110 @default.
• W4367011894 cites W2905224040 @default.
• W4367011894 cites W2938797369 @default.
• W4367011894 cites W2982379493 @default.
• W4367011894 cites W3141441229 @default.
• W4367011894 cites W3168985467 @default.
• W4367011894 cites W653885105 @default.
• W4367011894 doi "https://doi.org/10.1039/d3dt00563a" @default.
• W4367011894 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37098843" @default.
• W4367011894 hasPublicationYear "2023" @default.
• W4367011894 type Work @default.
• W4367011894 citedByCount "0" @default.
• W4367011894 crossrefType "journal-article" @default.
• W4367011894 hasAuthorship W4367011894A5005234987 @default.
• W4367011894 hasAuthorship W4367011894A5011576885 @default.
• W4367011894 hasAuthorship W4367011894A5041779175 @default.
• W4367011894 hasAuthorship W4367011894A5076200264 @default.
• W4367011894 hasConcept C104779481 @default.
• W4367011894 hasConcept C116569031 @default.
• W4367011894 hasConcept C120809312 @default.
• W4367011894 hasConcept C13965031 @default.
• W4367011894 hasConcept C140205800 @default.
• W4367011894 hasConcept C159985019 @default.
• W4367011894 hasConcept C170493617 @default.
• W4367011894 hasConcept C178790620 @default.
• W4367011894 hasConcept C179104552 @default.
• W4367011894 hasConcept C185592680 @default.
• W4367011894 hasConcept C192562407 @default.
• W4367011894 hasConcept C2775896084 @default.
• W4367011894 hasConcept C2776432453 @default.
• W4367011894 hasConcept C2780659211 @default.
• W4367011894 hasConcept C45812177 @default.
• W4367011894 hasConcept C530467964 @default.
• W4367011894 hasConcept C55493867 @default.
• W4367011894 hasConceptScore W4367011894C104779481 @default.
• W4367011894 hasConceptScore W4367011894C116569031 @default.
• W4367011894 hasConceptScore W4367011894C120809312 @default.
• W4367011894 hasConceptScore W4367011894C13965031 @default.
• W4367011894 hasConceptScore W4367011894C140205800 @default.
• W4367011894 hasConceptScore W4367011894C159985019 @default.
• W4367011894 hasConceptScore W4367011894C170493617 @default.
• W4367011894 hasConceptScore W4367011894C178790620 @default.
• W4367011894 hasConceptScore W4367011894C179104552 @default.
• W4367011894 hasConceptScore W4367011894C185592680 @default.
• W4367011894 hasConceptScore W4367011894C192562407 @default.
• W4367011894 hasConceptScore W4367011894C2775896084 @default.
• W4367011894 hasConceptScore W4367011894C2776432453 @default.
• W4367011894 hasConceptScore W4367011894C2780659211 @default.
• W4367011894 hasConceptScore W4367011894C45812177 @default.
• W4367011894 hasConceptScore W4367011894C530467964 @default.
• W4367011894 hasConceptScore W4367011894C55493867 @default.
• W4367011894 hasFunder F4320334841 @default.
• W4367011894 hasIssue "19" @default.
• W4367011894 hasLocation W43670118941 @default.
• W4367011894 hasLocation W43670118942 @default.
• W4367011894 hasOpenAccess W4367011894 @default.
• W4367011894 hasPrimaryLocation W43670118941 @default.
• W4367011894 hasRelatedWork W1983297918 @default.
• W4367011894 hasRelatedWork W2028567785 @default.
• W4367011894 hasRelatedWork W2038552269 @default.
• W4367011894 hasRelatedWork W2082951189 @default.

• next