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- W4367043309 abstract "Rare earth ARE2X4 (A = Cd, Mg; RE = Ho, Er, Tm, Yb, Lu; X = S, Se) spinels were studied with quantum DFT calculations to investigate the electronic structure of these systems, primarily those related to Intermediate-Valence and Heavy-Fermion behavior. The ARE2X4 compounds have narrow 4f peaks; therefore, if these RE:4f peaks are close to the Fermi level, they could exhibit Intermediate-Valent and Heavy-Fermion character. With RE = Ho, Er, Tm, Lu, the compounds resulted in insulators, while RE = Yb presented metallicity, an Intermediate-Valent and Heavy-Fermion characters. When electron-doped, the ATm2X4 and AEr2X4 spinels were found to have a Heavy-Fermion character." @default.
- W4367043309 created "2023-04-27" @default.
- W4367043309 creator A5027277543 @default.
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- W4367043309 date "2023-08-01" @default.
- W4367043309 modified "2023-10-03" @default.
- W4367043309 title "Rare earth chalcospinels, electronic structure, intermediate-valent, and heavy-fermion character" @default.
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- W4367043309 doi "https://doi.org/10.1016/j.jssc.2023.124056" @default.
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