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- W4367043515 endingPage "119226" @default.
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- W4367043515 abstract "Supported olefin metathesis catalysts have attracted considerable interest for over two decades, regarding their facile separation, reusability and decreased product contamination. In this study two strategies toward synthesis of heterogeneous ruthenium-catalyst were explored using supported ionic liquid phase (SILP) and supported ionic liquid-like phase (SILLP) with multi-walled carbon nanotubes (MWCNTs) as a support. The structure of ionic liquids used for the construction of catalysts was varied regarding length of alkyl chain and anion in terms of providing influence on catalytic activity and stability as well as reaction product contamination. The activity of prepared catalysts was tested in ring-closing metathesis (RCM). The Ru-based SILLP catalyst demonstrated high performance (conversions >90 % in five reaction cycles), compared to SILP and [email protected] catalyst synthesized using unmodified MWCNTs, additionally decreasing the product contamination with Ru (14 ppm)." @default.
- W4367043515 created "2023-04-27" @default.
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- W4367043515 date "2023-07-01" @default.
- W4367043515 modified "2023-09-30" @default.
- W4367043515 title "Supported ionic liquids for effective ruthenium olefin metathesis" @default.
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- W4367043515 doi "https://doi.org/10.1016/j.apcata.2023.119226" @default.
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