Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367153985> ?p ?o ?g. }
- W4367153985 endingPage "14192" @default.
- W4367153985 startingPage "14179" @default.
- W4367153985 abstract "A study of luminescence and photochromic properties of (E)-2,3-bis(2,5-dimethylthiophen-3-yl)-5-(4-(pyrrolidin-1-yl)benzylidene)cyclopent-2-en-1-one, which is a diarylethene with a push-pull system between carbonyl and dimethylamino groups, was performed using time-resolved methods. The intramolecular charge transfer (ICT) process as well as 6π-electrocyclization and E-/Z-isomerization contribute to the complex light-induced properties of this molecule. Formation of unexpected short-lived intermediates was detected in the time range from 100 fs to 100 μs. A model based on two processes (additional photocyclization and interconversion between conformers) was proposed to rationalize this result. The key intermediates existing in the picosecond time domain are so-called precursors, which are proposed for both parallel (p) and anti-parallel (ap) isomers of the open form. In general, fast light-induced processes for the fluorescent diarylcyclopentenones are much more complicated than for the parent cyclopentenone-based DAE." @default.
- W4367153985 created "2023-04-28" @default.
- W4367153985 creator A5013478816 @default.
- W4367153985 creator A5015326035 @default.
- W4367153985 creator A5025087215 @default.
- W4367153985 creator A5026381407 @default.
- W4367153985 creator A5038553408 @default.
- W4367153985 creator A5053444505 @default.
- W4367153985 creator A5065323941 @default.
- W4367153985 creator A5067693945 @default.
- W4367153985 creator A5080553254 @default.
- W4367153985 creator A5086295021 @default.
- W4367153985 date "2023-01-01" @default.
- W4367153985 modified "2023-10-14" @default.
- W4367153985 title "Multifunctional fluorescent diarylethene: time-resolved study of photochemistry" @default.
- W4367153985 cites W1613759268 @default.
- W4367153985 cites W1872248849 @default.
- W4367153985 cites W1976984447 @default.
- W4367153985 cites W1979140421 @default.
- W4367153985 cites W1986176923 @default.
- W4367153985 cites W1987562165 @default.
- W4367153985 cites W2001309031 @default.
- W4367153985 cites W2020926230 @default.
- W4367153985 cites W2021884442 @default.
- W4367153985 cites W2026465594 @default.
- W4367153985 cites W2026546864 @default.
- W4367153985 cites W2046092846 @default.
- W4367153985 cites W2046965007 @default.
- W4367153985 cites W2050305390 @default.
- W4367153985 cites W2054766586 @default.
- W4367153985 cites W2055725617 @default.
- W4367153985 cites W2063255047 @default.
- W4367153985 cites W2064696720 @default.
- W4367153985 cites W2065781120 @default.
- W4367153985 cites W2071796948 @default.
- W4367153985 cites W2074058482 @default.
- W4367153985 cites W2078948945 @default.
- W4367153985 cites W2080948719 @default.
- W4367153985 cites W2084856161 @default.
- W4367153985 cites W2087219880 @default.
- W4367153985 cites W2090329067 @default.
- W4367153985 cites W2092469837 @default.
- W4367153985 cites W2103396863 @default.
- W4367153985 cites W2111360758 @default.
- W4367153985 cites W2132179302 @default.
- W4367153985 cites W2144554101 @default.
- W4367153985 cites W2159215382 @default.
- W4367153985 cites W2160384475 @default.
- W4367153985 cites W2162915475 @default.
- W4367153985 cites W2256065944 @default.
- W4367153985 cites W2319662268 @default.
- W4367153985 cites W2321077391 @default.
- W4367153985 cites W2331283941 @default.
- W4367153985 cites W2517059366 @default.
- W4367153985 cites W2533608121 @default.
- W4367153985 cites W2565953970 @default.
- W4367153985 cites W2609030622 @default.
- W4367153985 cites W2750978322 @default.
- W4367153985 cites W2768469316 @default.
- W4367153985 cites W2888431899 @default.
- W4367153985 cites W2890147606 @default.
- W4367153985 cites W2981471133 @default.
- W4367153985 cites W2986141554 @default.
- W4367153985 cites W2997231975 @default.
- W4367153985 cites W3001946510 @default.
- W4367153985 cites W3004507473 @default.
- W4367153985 cites W3007821803 @default.
- W4367153985 cites W3087642562 @default.
- W4367153985 cites W3112973265 @default.
- W4367153985 cites W3121837479 @default.
- W4367153985 cites W3146588102 @default.
- W4367153985 cites W3178274734 @default.
- W4367153985 cites W3203838281 @default.
- W4367153985 cites W3204387288 @default.
- W4367153985 cites W4210761553 @default.
- W4367153985 cites W4309242794 @default.
- W4367153985 cites W569364877 @default.
- W4367153985 doi "https://doi.org/10.1039/d2cp05922c" @default.
- W4367153985 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37165694" @default.
- W4367153985 hasPublicationYear "2023" @default.
- W4367153985 type Work @default.
- W4367153985 citedByCount "1" @default.
- W4367153985 crossrefType "journal-article" @default.
- W4367153985 hasAuthorship W4367153985A5013478816 @default.
- W4367153985 hasAuthorship W4367153985A5015326035 @default.
- W4367153985 hasAuthorship W4367153985A5025087215 @default.
- W4367153985 hasAuthorship W4367153985A5026381407 @default.
- W4367153985 hasAuthorship W4367153985A5038553408 @default.
- W4367153985 hasAuthorship W4367153985A5053444505 @default.
- W4367153985 hasAuthorship W4367153985A5065323941 @default.
- W4367153985 hasAuthorship W4367153985A5067693945 @default.
- W4367153985 hasAuthorship W4367153985A5080553254 @default.
- W4367153985 hasAuthorship W4367153985A5086295021 @default.
- W4367153985 hasConcept C120665830 @default.
- W4367153985 hasConcept C121332964 @default.
- W4367153985 hasConcept C126661725 @default.
- W4367153985 hasConcept C148869448 @default.
- W4367153985 hasConcept C161790260 @default.