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• W4367173637 abstract "We report herein a tandem reaction of para-quinone methides with TMSCF2Br to construct bromofluoroalkenes in a Z-selective manner. While TMSCF2Br has been documented as the precursor of difluoro carbene, it exhibits another possibility in this transformation, a formal bromofluoro carbene surrogate. The alkenyl bromide unit of the products could directly engage in a variety of transformations." @default.
• W4367173637 created "2023-04-28" @default.
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• W4367173637 date "2023-04-27" @default.
• W4367173637 modified "2023-10-01" @default.
• W4367173637 title "(<i>Z</i>)-Selective Synthesis of Bromofluoroalkenes via the TMSCF₂Br-Mediated Tandem Reaction with <i>para</i>-Quinone Methides" @default.
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• W4367173637 doi "https://doi.org/10.1021/acs.orglett.3c01007" @default.
• W4367173637 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37104568" @default.
• W4367173637 hasPublicationYear "2023" @default.
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