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- W4367174503 abstract "Polyquinane sesquiterpenoids (PQSTs) are complex compounds with two or three fused cabocyclopentane ring systems, and the biocatalysts for direct C–H bond oxidation on these scaffolds have rarely been discovered. In this study, we discovered two versatile fungal CYP450s capable of performing diverse oxidations on seven PQST scaffolds, resulting in the generation of 20 unique products. Our findings significantly expand the diversity of oxidized PQST scaffolds and provide important biocatalysts for the selective oxidation of inert carbons of terpenoids in future research." @default.
- W4367174503 created "2023-04-28" @default.
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- W4367174503 date "2023-04-27" @default.
- W4367174503 modified "2023-09-27" @default.
- W4367174503 title "Reshaping the Diversity of Oxidized Polyquinane Sesquiterpenoids by Cytochrome P450s" @default.
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- W4367174503 doi "https://doi.org/10.1021/acs.orglett.3c01024" @default.
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