Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367296013> ?p ?o ?g. }
- W4367296013 endingPage "138746" @default.
- W4367296013 startingPage "138746" @default.
- W4367296013 abstract "Cu-loaded zeolites are widely investigated in selective catalytic reduction of nitrogen oxide, but effects of zeolite topologies on formed active species and the changing tendency remain unexplored. In this work, catalytic turnover frequencies (TOF) of Cu loaded ZSM-5, Beta, MOR, and SSZ-13 were first determined. The topology-localized Cu species in these zeolites were analyzed by temperature-programmed reduction of H2. Then Multiple Linear Regression distinguished TOF contributions (kj, s-1·mol-1) of the Cu species. Density functional theory calculated NH3 dehydrogenation energy of the Cu species. As a result, topologies with more node atoms showed bigger kj and lower dehydrogenation energies simultaneously. The best topology in each zeolite was 10-membered ring (ZSM-5), 6-membered ring facing a 12-membered ring (Beta), 8-membered ring (MOR), and cha cage (SSZ-13). Moreover, cha cage-localized Cu2+ exhibited the largest kj and the lowest dehydrogenation energy among all the Cu species. This work reveals topology-catalysis relationships in the zeolite, which benefits zeolite design for enhanced catalytic performances." @default.
- W4367296013 created "2023-04-29" @default.
- W4367296013 creator A5013294563 @default.
- W4367296013 creator A5019423710 @default.
- W4367296013 creator A5020543183 @default.
- W4367296013 creator A5033134884 @default.
- W4367296013 creator A5040035999 @default.
- W4367296013 creator A5056489746 @default.
- W4367296013 creator A5057055806 @default.
- W4367296013 creator A5080191032 @default.
- W4367296013 date "2023-08-01" @default.
- W4367296013 modified "2023-09-27" @default.
- W4367296013 title "Recognizing zeolite topologies for Cu2+ localizations with effective activities for selective catalytic reduction of nitrogen oxide" @default.
- W4367296013 cites W1994139661 @default.
- W4367296013 cites W1995624706 @default.
- W4367296013 cites W2007566391 @default.
- W4367296013 cites W2014603144 @default.
- W4367296013 cites W2033754073 @default.
- W4367296013 cites W2035316319 @default.
- W4367296013 cites W2049675237 @default.
- W4367296013 cites W2075736882 @default.
- W4367296013 cites W2084076310 @default.
- W4367296013 cites W2164337680 @default.
- W4367296013 cites W2277989806 @default.
- W4367296013 cites W2370585905 @default.
- W4367296013 cites W2601226039 @default.
- W4367296013 cites W2617486518 @default.
- W4367296013 cites W2761357927 @default.
- W4367296013 cites W2792670524 @default.
- W4367296013 cites W2888736730 @default.
- W4367296013 cites W2899456533 @default.
- W4367296013 cites W2902930103 @default.
- W4367296013 cites W2924753393 @default.
- W4367296013 cites W2942821374 @default.
- W4367296013 cites W2981886173 @default.
- W4367296013 cites W2986242244 @default.
- W4367296013 cites W3002723829 @default.
- W4367296013 cites W3008511673 @default.
- W4367296013 cites W3021313959 @default.
- W4367296013 cites W3027885283 @default.
- W4367296013 cites W3041815606 @default.
- W4367296013 cites W3045784547 @default.
- W4367296013 cites W3164262167 @default.
- W4367296013 cites W3196579299 @default.
- W4367296013 cites W3216298099 @default.
- W4367296013 cites W4200134260 @default.
- W4367296013 cites W4200512476 @default.
- W4367296013 cites W4214481363 @default.
- W4367296013 cites W4224312785 @default.
- W4367296013 cites W4225257240 @default.
- W4367296013 cites W4285743984 @default.
- W4367296013 cites W4285810612 @default.
- W4367296013 cites W4288032519 @default.
- W4367296013 cites W4294622193 @default.
- W4367296013 cites W4300003015 @default.
- W4367296013 cites W4311993706 @default.
- W4367296013 doi "https://doi.org/10.1016/j.chemosphere.2023.138746" @default.
- W4367296013 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37121281" @default.
- W4367296013 hasPublicationYear "2023" @default.
- W4367296013 type Work @default.
- W4367296013 citedByCount "0" @default.
- W4367296013 crossrefType "journal-article" @default.
- W4367296013 hasAuthorship W4367296013A5013294563 @default.
- W4367296013 hasAuthorship W4367296013A5019423710 @default.
- W4367296013 hasAuthorship W4367296013A5020543183 @default.
- W4367296013 hasAuthorship W4367296013A5033134884 @default.
- W4367296013 hasAuthorship W4367296013A5040035999 @default.
- W4367296013 hasAuthorship W4367296013A5056489746 @default.
- W4367296013 hasAuthorship W4367296013A5057055806 @default.
- W4367296013 hasAuthorship W4367296013A5080191032 @default.
- W4367296013 hasConcept C114614502 @default.
- W4367296013 hasConcept C119889771 @default.
- W4367296013 hasConcept C147789679 @default.
- W4367296013 hasConcept C161790260 @default.
- W4367296013 hasConcept C178790620 @default.
- W4367296013 hasConcept C179104552 @default.
- W4367296013 hasConcept C184720557 @default.
- W4367296013 hasConcept C185592680 @default.
- W4367296013 hasConcept C2778077586 @default.
- W4367296013 hasConcept C2779851234 @default.
- W4367296013 hasConcept C2780378348 @default.
- W4367296013 hasConcept C33923547 @default.
- W4367296013 hasConcept C537208039 @default.
- W4367296013 hasConcept C95121573 @default.
- W4367296013 hasConceptScore W4367296013C114614502 @default.
- W4367296013 hasConceptScore W4367296013C119889771 @default.
- W4367296013 hasConceptScore W4367296013C147789679 @default.
- W4367296013 hasConceptScore W4367296013C161790260 @default.
- W4367296013 hasConceptScore W4367296013C178790620 @default.
- W4367296013 hasConceptScore W4367296013C179104552 @default.
- W4367296013 hasConceptScore W4367296013C184720557 @default.
- W4367296013 hasConceptScore W4367296013C185592680 @default.
- W4367296013 hasConceptScore W4367296013C2778077586 @default.
- W4367296013 hasConceptScore W4367296013C2779851234 @default.
- W4367296013 hasConceptScore W4367296013C2780378348 @default.
- W4367296013 hasConceptScore W4367296013C33923547 @default.
- W4367296013 hasConceptScore W4367296013C537208039 @default.
- W4367296013 hasConceptScore W4367296013C95121573 @default.