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• W4367302021 endingPage "3238" @default.
• W4367302021 startingPage "3209" @default.
• W4367302021 abstract "Abstract Silyl esters have been exploited as metastable reaction intermediates, both purposefully and unintentionally, since at least the 1960s. Their reactivity is broadly related to the substituents on the silicon, and in this way their properties can be readily modulated. Silyl esters have unique reactivity profiles that have been used to generate downstream products of a range of functionalities, and because of this many excellent methods for the synthesis of a variety of value-added chemicals have been developed. Furthermore, because of the frequent use of hydrosilanes as terminal reductants in catalytic processes, silyl ester intermediates are likely more commonly utilized by synthetic chemists than currently realized. This review comprehensively summarizes the reactions known to take advantage of reactive silyl ester intermediates and discusses examples of catalytic reactions that proceed in an unanticipated manner through silyl ester intermediates. 1 Introduction 2 Synthesis of Silyl Esters 3 Making Amides from Silyl Esters 3.1 Amidation Using Chlorosilanes 3.2 Amidation Using Azasilanes 3.3 Amidation Using Oxysilanes 3.4 Amidation Using Hydrosilanes 3.5 Amine Formation via Amidation/Reduction 3.6 Miscellaneous 4 Mechanistic Investigations of Amidation 4.1 Mechanism of Amidation Using Chlorosilanes 4.2 Mechanism of Amidation Using Hydrosilanes 4.3 Mechanism of Amidation Using Oxy- or Azasilanes 5 Making Esters from Silyl Esters 6 Making Aldehydes, Alcohols, Amines, and Alkanes via Reduction 6.1 Aldehyde Synthesis by Metal-Free Reduction 6.2 Aldehyde Synthesis by Metal-Mediated Reduction 6.3 Alcohol Synthesis by Metal-Mediated Reduction 6.4 Amine Synthesis 6.5 Alkane Synthesis by Metal-Free Reduction 7 Making Acid Chlorides from Silyl Esters 8 In Situ Generated Silyl Esters and Ramifications for Catalysis 9 Conclusion" @default.
• W4367302021 created "2023-04-29" @default.
• W4367302021 creator A5023379361 @default.
• W4367302021 creator A5025870305 @default.
• W4367302021 creator A5050526074 @default.
• W4367302021 creator A5079296829 @default.
• W4367302021 date "2023-04-28" @default.
• W4367302021 modified "2023-09-29" @default.
• W4367302021 title "Silyl Esters as Reactive Intermediates in Organic Synthesis" @default.
• W4367302021 cites W1897147312 @default.
• W4367302021 cites W1964141032 @default.
• W4367302021 cites W1971373704 @default.
• W4367302021 cites W1975457321 @default.
• W4367302021 cites W1979718552 @default.
• W4367302021 cites W1986925832 @default.
• W4367302021 cites W1987158453 @default.
• W4367302021 cites W1993200858 @default.
• W4367302021 cites W1993233047 @default.
• W4367302021 cites W2001341516 @default.
• W4367302021 cites W2003699803 @default.
• W4367302021 cites W2009920453 @default.
• W4367302021 cites W2011624667 @default.
• W4367302021 cites W2012306698 @default.
• W4367302021 cites W2017506918 @default.
• W4367302021 cites W2019848076 @default.
• W4367302021 cites W2020758236 @default.
• W4367302021 cites W2022543673 @default.
• W4367302021 cites W2022930922 @default.
• W4367302021 cites W2030481316 @default.
• W4367302021 cites W2031734182 @default.
• W4367302021 cites W2033868550 @default.
• W4367302021 cites W2036819735 @default.
• W4367302021 cites W2046297661 @default.
• W4367302021 cites W2047558684 @default.
• W4367302021 cites W2051969502 @default.
• W4367302021 cites W2053967928 @default.
• W4367302021 cites W2057168323 @default.
• W4367302021 cites W2068330397 @default.
• W4367302021 cites W2071866384 @default.
• W4367302021 cites W2086260105 @default.
• W4367302021 cites W2087691378 @default.
• W4367302021 cites W2102943700 @default.
• W4367302021 cites W2117180484 @default.
• W4367302021 cites W2117757867 @default.
• W4367302021 cites W2136726885 @default.
• W4367302021 cites W2137461269 @default.
• W4367302021 cites W2138514539 @default.
• W4367302021 cites W2148129267 @default.
• W4367302021 cites W2155810941 @default.
• W4367302021 cites W2179356784 @default.
• W4367302021 cites W2195179033 @default.
• W4367302021 cites W2236631406 @default.
• W4367302021 cites W2313880395 @default.
• W4367302021 cites W2314216178 @default.
• W4367302021 cites W2332052012 @default.
• W4367302021 cites W2497470437 @default.
• W4367302021 cites W2523045592 @default.
• W4367302021 cites W2527971256 @default.
• W4367302021 cites W2530788502 @default.
• W4367302021 cites W2559880835 @default.
• W4367302021 cites W2563934114 @default.
• W4367302021 cites W2616057797 @default.
• W4367302021 cites W2667655382 @default.
• W4367302021 cites W2744314957 @default.
• W4367302021 cites W2758498026 @default.
• W4367302021 cites W2760233773 @default.
• W4367302021 cites W2763134411 @default.
• W4367302021 cites W2787196046 @default.
• W4367302021 cites W2801298295 @default.
• W4367302021 cites W2808590181 @default.
• W4367302021 cites W2895265773 @default.
• W4367302021 cites W2899450793 @default.
• W4367302021 cites W2907062783 @default.
• W4367302021 cites W2913883376 @default.
• W4367302021 cites W2941833243 @default.
• W4367302021 cites W2949861234 @default.
• W4367302021 cites W2950083522 @default.
• W4367302021 cites W2950098773 @default.
• W4367302021 cites W2950761199 @default.
• W4367302021 cites W2951343196 @default.
• W4367302021 cites W2952938483 @default.
• W4367302021 cites W2953165920 @default.
• W4367302021 cites W2965398658 @default.
• W4367302021 cites W2973600193 @default.
• W4367302021 cites W2979142215 @default.
• W4367302021 cites W2979975863 @default.
• W4367302021 cites W2982108360 @default.
• W4367302021 cites W2994634793 @default.
• W4367302021 cites W2995222523 @default.
• W4367302021 cites W2997894949 @default.
• W4367302021 cites W3016452969 @default.
• W4367302021 cites W3046354178 @default.
• W4367302021 cites W3048697903 @default.
• W4367302021 cites W3108708985 @default.
• W4367302021 cites W3146410142 @default.
• W4367302021 cites W3163258816 @default.
• W4367302021 cites W3165091792 @default.
• W4367302021 cites W3186489413 @default.

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