FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367308752> ?p ?o ?g. }

• W4367308752 endingPage "128493" @default.
• W4367308752 startingPage "128493" @default.
• W4367308752 abstract "The chemical conversion of inert carbon dioxide (CO2) into high value-added chemicals is a continuing challenge. In this work, an experimental and theoretical mechanism study is presented for one-pot synthesis of glycerol carbonate (GC) from CO2, glycerol (Gly), and propylene epoxide (PO) catalyzed by 1,8-diazabicyclo[5.4.0]undec-7-enenium iodide (HDBUI) ionic liquid. 92% GC yield was obtained in the one-pot reaction through cycloaddition of CO2 with PO to produce propylene carbonate (PC), followed by transesterification of Gly with PC to yield targeted products. Density functional theory (DFT) calculations were used to unveil the HDBUI-mediated catalytic mechanism and key catalytic species. It was revealed that the HDBUI-catalyzed cycloaddition was assisted by the hydrogen bond donor Gly, the transesterification reactant, by promoting the ring-opening of PO and the insertion of CO2. By activating Gly hydroxyl group, alkaline HDBUI-bonded propan-1-ylium-2-yl carbonate, an intermediate in cycloaddition, catalyzed transesterification. The complementary mechanism of cycloaddition and transesterification in the one-pot provides a feasible method for utilizing inert CO2." @default.
• W4367308752 created "2023-04-29" @default.
• W4367308752 creator A5000537039 @default.
• W4367308752 creator A5003769106 @default.
• W4367308752 creator A5011086470 @default.
• W4367308752 creator A5042151909 @default.
• W4367308752 creator A5047765176 @default.
• W4367308752 creator A5072142807 @default.
• W4367308752 creator A5079396437 @default.
• W4367308752 creator A5083773471 @default.
• W4367308752 creator A5086269921 @default.
• W4367308752 date "2023-09-01" @default.
• W4367308752 modified "2023-09-28" @default.
• W4367308752 title "Unveiling the complementary mechanism in the one-pot synthesis of glycerol carbonate from CO2 and glycerol" @default.
• W4367308752 cites W1966949133 @default.
• W4367308752 cites W1976161355 @default.
• W4367308752 cites W2036717420 @default.
• W4367308752 cites W2050081896 @default.
• W4367308752 cites W2071632181 @default.
• W4367308752 cites W2094413778 @default.
• W4367308752 cites W2116965144 @default.
• W4367308752 cites W2120311061 @default.
• W4367308752 cites W2132525235 @default.
• W4367308752 cites W2171836549 @default.
• W4367308752 cites W2172026094 @default.
• W4367308752 cites W2470501659 @default.
• W4367308752 cites W2499543034 @default.
• W4367308752 cites W2556792966 @default.
• W4367308752 cites W2746168731 @default.
• W4367308752 cites W2770577765 @default.
• W4367308752 cites W2786375019 @default.
• W4367308752 cites W2788567766 @default.
• W4367308752 cites W2899096452 @default.
• W4367308752 cites W2902154532 @default.
• W4367308752 cites W2908169377 @default.
• W4367308752 cites W2946602721 @default.
• W4367308752 cites W2982007527 @default.
• W4367308752 cites W2988278250 @default.
• W4367308752 cites W3092047529 @default.
• W4367308752 cites W3114428603 @default.
• W4367308752 cites W3162238906 @default.
• W4367308752 cites W3204707566 @default.
• W4367308752 cites W4205746067 @default.
• W4367308752 cites W4292199312 @default.
• W4367308752 cites W4292308255 @default.
• W4367308752 cites W4293257158 @default.
• W4367308752 cites W4311087463 @default.
• W4367308752 doi "https://doi.org/10.1016/j.fuel.2023.128493" @default.
• W4367308752 hasPublicationYear "2023" @default.
• W4367308752 type Work @default.
• W4367308752 citedByCount "1" @default.
• W4367308752 crossrefType "journal-article" @default.
• W4367308752 hasAuthorship W4367308752A5000537039 @default.
• W4367308752 hasAuthorship W4367308752A5003769106 @default.
• W4367308752 hasAuthorship W4367308752A5011086470 @default.
• W4367308752 hasAuthorship W4367308752A5042151909 @default.
• W4367308752 hasAuthorship W4367308752A5047765176 @default.
• W4367308752 hasAuthorship W4367308752A5072142807 @default.
• W4367308752 hasAuthorship W4367308752A5079396437 @default.
• W4367308752 hasAuthorship W4367308752A5083773471 @default.
• W4367308752 hasAuthorship W4367308752A5086269921 @default.
• W4367308752 hasConcept C147789679 @default.
• W4367308752 hasConcept C154881586 @default.
• W4367308752 hasConcept C161790260 @default.
• W4367308752 hasConcept C17525397 @default.
• W4367308752 hasConcept C178790620 @default.
• W4367308752 hasConcept C185592680 @default.
• W4367308752 hasConcept C2776920199 @default.
• W4367308752 hasConcept C2777241282 @default.
• W4367308752 hasConcept C2777983707 @default.
• W4367308752 hasConcept C2778197717 @default.
• W4367308752 hasConcept C2779664164 @default.
• W4367308752 hasConcept C2780659211 @default.
• W4367308752 hasConcept C2780881558 @default.
• W4367308752 hasConcept C2781326009 @default.
• W4367308752 hasConcept C52859227 @default.
• W4367308752 hasConceptScore W4367308752C147789679 @default.
• W4367308752 hasConceptScore W4367308752C154881586 @default.
• W4367308752 hasConceptScore W4367308752C161790260 @default.
• W4367308752 hasConceptScore W4367308752C17525397 @default.
• W4367308752 hasConceptScore W4367308752C178790620 @default.
• W4367308752 hasConceptScore W4367308752C185592680 @default.
• W4367308752 hasConceptScore W4367308752C2776920199 @default.
• W4367308752 hasConceptScore W4367308752C2777241282 @default.
• W4367308752 hasConceptScore W4367308752C2777983707 @default.
• W4367308752 hasConceptScore W4367308752C2778197717 @default.
• W4367308752 hasConceptScore W4367308752C2779664164 @default.
• W4367308752 hasConceptScore W4367308752C2780659211 @default.
• W4367308752 hasConceptScore W4367308752C2780881558 @default.
• W4367308752 hasConceptScore W4367308752C2781326009 @default.
• W4367308752 hasConceptScore W4367308752C52859227 @default.
• W4367308752 hasLocation W43673087521 @default.
• W4367308752 hasOpenAccess W4367308752 @default.
• W4367308752 hasPrimaryLocation W43673087521 @default.
• W4367308752 hasRelatedWork W2047640424 @default.
• W4367308752 hasRelatedWork W2061964912 @default.
• W4367308752 hasRelatedWork W2071864537 @default.
• W4367308752 hasRelatedWork W2789269525 @default.

• next