Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367311806> ?p ?o ?g. }
- W4367311806 endingPage "3804" @default.
- W4367311806 startingPage "3804" @default.
- W4367311806 abstract "The effect of the terminal benzyloxy group on the mesomorphic properties of liquid crystalline materials developed from rod-like Schiff base has been described. For this objective, a novel Schiff base liquid crystal family, specifically new series of Schiff base liquid crystals, namely, (E)-4-(alkyloxy)-N-(4-(benzyloxy)benzylidene)aniline, In, are prepared and investigated in detail. The length of the terminal alkyloxy chain (n) varies amongst the compounds in the series. Where n varies between 6, 8 and 16 carbons. At the other end of the compounds, benzyloxy moiety was attached. The molecular structures of all synthesized compounds were established using different spectroscopic techniques. The molecular self-assembly was explored using differential scanning calorimetry (DSC) and polarized optical microscope (POM). Depending on the length of the terminal alkyloxy chain, only one type of SmA phase with different stability was observed. The previously reported para-substituted systems and the present investigated compounds were compared and discussed. The calculated quantum chemical parameters were computationally correlated using the DFT method via the B3LYP 6-311G(d,p) basis set. The theoretical computations revealed that the length of the alkyl side chain influences the zero-point energy, reactivity and other estimated thermodynamic parameters of benzoyloxy/azomethine derivatives. Furthermore, the FMO energy analysis shows that molecule I16 have higher HOMO energies than the other compounds, and I6 has a much lower LUMO level than the rest." @default.
- W4367311806 created "2023-04-29" @default.
- W4367311806 creator A5019548652 @default.
- W4367311806 creator A5053844922 @default.
- W4367311806 creator A5057067213 @default.
- W4367311806 creator A5059716628 @default.
- W4367311806 creator A5069840153 @default.
- W4367311806 creator A5075951547 @default.
- W4367311806 date "2023-04-28" @default.
- W4367311806 modified "2023-09-27" @default.
- W4367311806 title "Synthesis of New Liquid-Crystalline Compounds Based on Terminal Benzyloxy Group: Characterization, DFT and Mesomorphic Properties" @default.
- W4367311806 cites W1550294169 @default.
- W4367311806 cites W1974140662 @default.
- W4367311806 cites W1983778577 @default.
- W4367311806 cites W2009223857 @default.
- W4367311806 cites W2023271753 @default.
- W4367311806 cites W2039868264 @default.
- W4367311806 cites W2048546724 @default.
- W4367311806 cites W2049049473 @default.
- W4367311806 cites W2050597520 @default.
- W4367311806 cites W2055547916 @default.
- W4367311806 cites W2063644787 @default.
- W4367311806 cites W2064346857 @default.
- W4367311806 cites W2064554388 @default.
- W4367311806 cites W2072243343 @default.
- W4367311806 cites W2078300444 @default.
- W4367311806 cites W2095567012 @default.
- W4367311806 cites W2114971335 @default.
- W4367311806 cites W2125087233 @default.
- W4367311806 cites W2138516411 @default.
- W4367311806 cites W2143981217 @default.
- W4367311806 cites W2145878327 @default.
- W4367311806 cites W2463801883 @default.
- W4367311806 cites W2611250068 @default.
- W4367311806 cites W2729402322 @default.
- W4367311806 cites W2741286501 @default.
- W4367311806 cites W2781996362 @default.
- W4367311806 cites W2784535867 @default.
- W4367311806 cites W2791929626 @default.
- W4367311806 cites W2794207295 @default.
- W4367311806 cites W3112392269 @default.
- W4367311806 cites W3150822742 @default.
- W4367311806 cites W3161828466 @default.
- W4367311806 cites W3163187681 @default.
- W4367311806 cites W3167185276 @default.
- W4367311806 cites W3175031206 @default.
- W4367311806 cites W3185489524 @default.
- W4367311806 cites W3197046435 @default.
- W4367311806 cites W4206900514 @default.
- W4367311806 cites W4220902836 @default.
- W4367311806 cites W4281692953 @default.
- W4367311806 cites W4282827043 @default.
- W4367311806 cites W4283701281 @default.
- W4367311806 cites W4289313898 @default.
- W4367311806 cites W4311944984 @default.
- W4367311806 cites W4313252828 @default.
- W4367311806 cites W4321598548 @default.
- W4367311806 cites W4360942506 @default.
- W4367311806 doi "https://doi.org/10.3390/molecules28093804" @default.
- W4367311806 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37175214" @default.
- W4367311806 hasPublicationYear "2023" @default.
- W4367311806 type Work @default.
- W4367311806 citedByCount "4" @default.
- W4367311806 countsByYear W43673118062023 @default.
- W4367311806 crossrefType "journal-article" @default.
- W4367311806 hasAuthorship W4367311806A5019548652 @default.
- W4367311806 hasAuthorship W4367311806A5053844922 @default.
- W4367311806 hasAuthorship W4367311806A5057067213 @default.
- W4367311806 hasAuthorship W4367311806A5059716628 @default.
- W4367311806 hasAuthorship W4367311806A5069840153 @default.
- W4367311806 hasAuthorship W4367311806A5075951547 @default.
- W4367311806 hasBestOaLocation W43673118061 @default.
- W4367311806 hasConcept C121332964 @default.
- W4367311806 hasConcept C13274807 @default.
- W4367311806 hasConcept C13530604 @default.
- W4367311806 hasConcept C14158195 @default.
- W4367311806 hasConcept C178790620 @default.
- W4367311806 hasConcept C185592680 @default.
- W4367311806 hasConcept C192562407 @default.
- W4367311806 hasConcept C2776428424 @default.
- W4367311806 hasConcept C2776482079 @default.
- W4367311806 hasConcept C2776568683 @default.
- W4367311806 hasConcept C2779244968 @default.
- W4367311806 hasConcept C2780263894 @default.
- W4367311806 hasConcept C32909587 @default.
- W4367311806 hasConcept C39519442 @default.
- W4367311806 hasConcept C44280652 @default.
- W4367311806 hasConcept C49040817 @default.
- W4367311806 hasConcept C71240020 @default.
- W4367311806 hasConcept C8010536 @default.
- W4367311806 hasConcept C97355855 @default.
- W4367311806 hasConceptScore W4367311806C121332964 @default.
- W4367311806 hasConceptScore W4367311806C13274807 @default.
- W4367311806 hasConceptScore W4367311806C13530604 @default.
- W4367311806 hasConceptScore W4367311806C14158195 @default.
- W4367311806 hasConceptScore W4367311806C178790620 @default.
- W4367311806 hasConceptScore W4367311806C185592680 @default.
- W4367311806 hasConceptScore W4367311806C192562407 @default.