Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367320281> ?p ?o ?g. }
- W4367320281 endingPage "2084" @default.
- W4367320281 startingPage "2084" @default.
- W4367320281 abstract "Composites based on an L-rich poly(lactic acid) (PLLA) and MCM-41, either neat or modified with a silver (MCM-41@Ag), are achieved by solvent casting, being next processed by compression molding. Ag is mainly embedded as nanowires within the hybrid MCM-41@Ag particles, enabling its antimicrobial character. In these composites, the PLLA thermal stability, nucleation efficiency, and mechanical response are dependent on the MCM-41 nature and, to a lesser extent, on its content. Thus, differences in transitions of the PLLA matrix are noticed during cooling at 10 °C/min and in the subsequent heating when composites with neat or modified MCM-41 are compared. A very remarkable nucleation effect is played by pristine MCM-41, being inferior when MCM-41@Ag is incorporated into the PLLA. Wide angle X-ray scattering (WAXS) measurements using synchrotron radiation and performed under variable-temperature conditions in the composites containing MCM-41@Ag indicate that during cold crystallization, the disordered α' polymorph is initially formed, but it rapidly transforms into ordered α crystals. A long spacing peak, clearly seen in pure PLLA, appears as a small shoulder in PLLAMCM@Ag4 and is undetectable in PLLAMCM@Ag9 and PLLAMCM@Ag20. Furthermore, an increase in MH with the silica content is found in the two sets of composites, the higher MH values being observed in the family of PLLA and MCM-41@Ag. Finally, remarkable antimicrobial features are noticeable in the composites with MCM-41@Ag since this modified silica transfers its biocidal characteristics into the PLLA composites." @default.
- W4367320281 created "2023-04-29" @default.
- W4367320281 creator A5004661245 @default.
- W4367320281 creator A5020276359 @default.
- W4367320281 creator A5031789908 @default.
- W4367320281 creator A5040839495 @default.
- W4367320281 creator A5066794822 @default.
- W4367320281 creator A5070673060 @default.
- W4367320281 date "2023-04-27" @default.
- W4367320281 modified "2023-10-14" @default.
- W4367320281 title "Antimicrobial Activity and Crystallization Features in Bio-Based Composites of PLLA and MCM-41 Particles Either Pristine or Functionalized with Confined Ag Nanowires" @default.
- W4367320281 cites W1922160453 @default.
- W4367320281 cites W1968952657 @default.
- W4367320281 cites W1969641831 @default.
- W4367320281 cites W1975090446 @default.
- W4367320281 cites W1976525237 @default.
- W4367320281 cites W1978020780 @default.
- W4367320281 cites W1982784029 @default.
- W4367320281 cites W1987039893 @default.
- W4367320281 cites W1987225832 @default.
- W4367320281 cites W1990235192 @default.
- W4367320281 cites W1992646262 @default.
- W4367320281 cites W1995041236 @default.
- W4367320281 cites W1996272320 @default.
- W4367320281 cites W2000405970 @default.
- W4367320281 cites W2009927324 @default.
- W4367320281 cites W2017595504 @default.
- W4367320281 cites W2019205181 @default.
- W4367320281 cites W2022351794 @default.
- W4367320281 cites W2027487510 @default.
- W4367320281 cites W2033791433 @default.
- W4367320281 cites W2035296584 @default.
- W4367320281 cites W2035512535 @default.
- W4367320281 cites W2039069620 @default.
- W4367320281 cites W2045300819 @default.
- W4367320281 cites W2048334491 @default.
- W4367320281 cites W2055575795 @default.
- W4367320281 cites W2058261287 @default.
- W4367320281 cites W2058473812 @default.
- W4367320281 cites W2068006593 @default.
- W4367320281 cites W2087600721 @default.
- W4367320281 cites W2093690283 @default.
- W4367320281 cites W2109452850 @default.
- W4367320281 cites W2111000138 @default.
- W4367320281 cites W2111836708 @default.
- W4367320281 cites W2130166311 @default.
- W4367320281 cites W2153073284 @default.
- W4367320281 cites W2161052679 @default.
- W4367320281 cites W2208152602 @default.
- W4367320281 cites W2315950804 @default.
- W4367320281 cites W2411921434 @default.
- W4367320281 cites W2553473658 @default.
- W4367320281 cites W2808723657 @default.
- W4367320281 cites W2810669174 @default.
- W4367320281 cites W2883779028 @default.
- W4367320281 cites W2896518416 @default.
- W4367320281 cites W2916524281 @default.
- W4367320281 cites W2964722796 @default.
- W4367320281 cites W2995036778 @default.
- W4367320281 cites W2998371256 @default.
- W4367320281 cites W3082097081 @default.
- W4367320281 cites W3104778785 @default.
- W4367320281 cites W3163344971 @default.
- W4367320281 cites W4200061442 @default.
- W4367320281 cites W4206175036 @default.
- W4367320281 cites W4206756586 @default.
- W4367320281 cites W4213320919 @default.
- W4367320281 cites W4220971256 @default.
- W4367320281 cites W4321190467 @default.
- W4367320281 cites W98999152 @default.
- W4367320281 doi "https://doi.org/10.3390/polym15092084" @default.
- W4367320281 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37177226" @default.
- W4367320281 hasPublicationYear "2023" @default.
- W4367320281 type Work @default.
- W4367320281 citedByCount "0" @default.
- W4367320281 crossrefType "journal-article" @default.
- W4367320281 hasAuthorship W4367320281A5004661245 @default.
- W4367320281 hasAuthorship W4367320281A5020276359 @default.
- W4367320281 hasAuthorship W4367320281A5031789908 @default.
- W4367320281 hasAuthorship W4367320281A5040839495 @default.
- W4367320281 hasAuthorship W4367320281A5066794822 @default.
- W4367320281 hasAuthorship W4367320281A5070673060 @default.
- W4367320281 hasBestOaLocation W43673202811 @default.
- W4367320281 hasConcept C104779481 @default.
- W4367320281 hasConcept C127413603 @default.
- W4367320281 hasConcept C159985019 @default.
- W4367320281 hasConcept C171250308 @default.
- W4367320281 hasConcept C178790620 @default.
- W4367320281 hasConcept C185592680 @default.
- W4367320281 hasConcept C186867162 @default.
- W4367320281 hasConcept C192562407 @default.
- W4367320281 hasConcept C203036418 @default.
- W4367320281 hasConcept C2780566776 @default.
- W4367320281 hasConcept C42360764 @default.
- W4367320281 hasConcept C59061564 @default.
- W4367320281 hasConcept C61048295 @default.
- W4367320281 hasConcept C74214498 @default.
- W4367320281 hasConcept C92880739 @default.