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- W4367355337 abstract "A one-pot electronically controlled [4 + 2] cycloaddition reaction of in situ generated benzyne with 2-arylidene-1-indenone is unveiled to construct novel spirocyclic frameworks in a regio- and diastereoselective fashion. This protocol features operational simplicity, good functional group tolerance and avoids the use of metal catalysts and external additives. This methodology has extended the synthetic application of 2-arylidene-1-indenones enabling easy access to valuable 10'H-spiro[indene-2,9'-phenanthren]-1(3H)-ones in good yields." @default.
- W4367355337 created "2023-04-30" @default.
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- W4367355337 date "2023-01-01" @default.
- W4367355337 modified "2023-10-01" @default.
- W4367355337 title "Electronically-Controlled Diastereoselective Synthesis of Spirocycles via [4+2] Cycloaddition of 2-arylidene-1-Indenones with Benzyne" @default.
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- W4367355337 doi "https://doi.org/10.1039/d3ob00417a" @default.
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