FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4367396600> ?p ?o ?g. }

• W4367396600 endingPage "127235" @default.
• W4367396600 startingPage "127235" @default.
• W4367396600 abstract "Experimental results of a study of the effect of concentration of Al(III) and Fe(III) ions on the metastable zone width (MSZW) of aqueous ADP saturated solutions, as determined by the maximum antisolvent content Δxmax in them for spontaneous three-dimensional (3D) nucleation, by feeding ethanol antisolvent to them at different rates RA and the nucleation and growth of crystals from these solutions are described and discussed. Crystal structure and segregation coefficients of impurity in the crystals were also studied by X-ray diffraction analysis and microwave plasma atomic absorption spectrometry, respectively. It was observed that: (1) the value of Δxmax for spontaneous 3D nucleation increases with an increase in ethanol feeding rate RA as well as impurity concentration ci, (2) the morphology and size of the ADP crystals changes with an increase in impurity concentration ci and antisolvent feeding rate RA, and (3) the effective segregation coefficients keff of the impurities in ADP crystals at a constant RA of ethanol feeding decreases with an increase in impurity concentration ci in the solution. The experimental data of the dependence of Δxmax on RA for solutions containing different impurity concentration ci were analyzed according to the approach based on the classical theory for 3D nucleation to calculate values of the preexponential factor A and the effective interfacial energy γeff of the theory, those of the morphology of ADP crystals from consideration of adsorption of impurity particles on the surfaces of growing crystals, and those of the dependence of segregation coefficient keff of the impurities on their concentration ci in the solution using a model based on competitive adsorption of solute and impurity molecules. It is argued that the formation of 3D nuclei of ADP during MSZW measurements and growth of these ADP nuclei as large crystals from aqueous solutions containing impurities and segregation of impurities in the crystals may be explained from consideration of different rates of ligand exchange of the surface-adsorbed complexes formed by interaction between univalently-charged cation complex present in aqueous solution and the H2PO4− ions of kinks in steps." @default.
• W4367396600 created "2023-04-30" @default.
• W4367396600 creator A5017225174 @default.
• W4367396600 creator A5025445879 @default.
• W4367396600 creator A5033952125 @default.
• W4367396600 creator A5061313416 @default.
• W4367396600 date "2023-07-01" @default.
• W4367396600 modified "2023-09-23" @default.
• W4367396600 title "Antisolvent crystallization of ammonium dihydrogen phosphate (ADP) from aqueous solutions containing Al(III) and Fe(III) impurities by addition of ethanol" @default.
• W4367396600 cites W1972161514 @default.
• W4367396600 cites W1975974465 @default.
• W4367396600 cites W1978397380 @default.
• W4367396600 cites W1981541422 @default.
• W4367396600 cites W1985679720 @default.
• W4367396600 cites W1998769627 @default.
• W4367396600 cites W2021969925 @default.
• W4367396600 cites W2030470398 @default.
• W4367396600 cites W2039712243 @default.
• W4367396600 cites W2058224536 @default.
• W4367396600 cites W2058827506 @default.
• W4367396600 cites W2075000056 @default.
• W4367396600 cites W2079658252 @default.
• W4367396600 cites W2082746567 @default.
• W4367396600 cites W2085220701 @default.
• W4367396600 cites W2086144925 @default.
• W4367396600 cites W2090163593 @default.
• W4367396600 cites W2090633046 @default.
• W4367396600 cites W2131351095 @default.
• W4367396600 cites W2151868199 @default.
• W4367396600 cites W2155991169 @default.
• W4367396600 cites W2160810152 @default.
• W4367396600 cites W2219318506 @default.
• W4367396600 cites W2462515669 @default.
• W4367396600 cites W2476847465 @default.
• W4367396600 cites W2622151292 @default.
• W4367396600 cites W2808553897 @default.
• W4367396600 cites W2954909468 @default.
• W4367396600 cites W3004066791 @default.
• W4367396600 cites W4290048553 @default.
• W4367396600 doi "https://doi.org/10.1016/j.jcrysgro.2023.127235" @default.
• W4367396600 hasPublicationYear "2023" @default.
• W4367396600 type Work @default.
• W4367396600 citedByCount "0" @default.
• W4367396600 crossrefType "journal-article" @default.
• W4367396600 hasAuthorship W4367396600A5017225174 @default.
• W4367396600 hasAuthorship W4367396600A5025445879 @default.
• W4367396600 hasAuthorship W4367396600A5033952125 @default.
• W4367396600 hasAuthorship W4367396600A5061313416 @default.
• W4367396600 hasConcept C113196181 @default.
• W4367396600 hasConcept C125287762 @default.
• W4367396600 hasConcept C147789679 @default.
• W4367396600 hasConcept C150394285 @default.
• W4367396600 hasConcept C159985019 @default.
• W4367396600 hasConcept C178790620 @default.
• W4367396600 hasConcept C184651966 @default.
• W4367396600 hasConcept C185592680 @default.
• W4367396600 hasConcept C192562407 @default.
• W4367396600 hasConcept C203036418 @default.
• W4367396600 hasConcept C2777751223 @default.
• W4367396600 hasConcept C2780560099 @default.
• W4367396600 hasConcept C43617362 @default.
• W4367396600 hasConcept C61048295 @default.
• W4367396600 hasConcept C71987851 @default.
• W4367396600 hasConcept C8010536 @default.
• W4367396600 hasConcept C89464430 @default.
• W4367396600 hasConceptScore W4367396600C113196181 @default.
• W4367396600 hasConceptScore W4367396600C125287762 @default.
• W4367396600 hasConceptScore W4367396600C147789679 @default.
• W4367396600 hasConceptScore W4367396600C150394285 @default.
• W4367396600 hasConceptScore W4367396600C159985019 @default.
• W4367396600 hasConceptScore W4367396600C178790620 @default.
• W4367396600 hasConceptScore W4367396600C184651966 @default.
• W4367396600 hasConceptScore W4367396600C185592680 @default.
• W4367396600 hasConceptScore W4367396600C192562407 @default.
• W4367396600 hasConceptScore W4367396600C203036418 @default.
• W4367396600 hasConceptScore W4367396600C2777751223 @default.
• W4367396600 hasConceptScore W4367396600C2780560099 @default.
• W4367396600 hasConceptScore W4367396600C43617362 @default.
• W4367396600 hasConceptScore W4367396600C61048295 @default.
• W4367396600 hasConceptScore W4367396600C71987851 @default.
• W4367396600 hasConceptScore W4367396600C8010536 @default.
• W4367396600 hasConceptScore W4367396600C89464430 @default.
• W4367396600 hasLocation W43673966001 @default.
• W4367396600 hasOpenAccess W4367396600 @default.
• W4367396600 hasPrimaryLocation W43673966001 @default.
• W4367396600 hasRelatedWork W2002577086 @default.
• W4367396600 hasRelatedWork W2008235193 @default.
• W4367396600 hasRelatedWork W2051601222 @default.
• W4367396600 hasRelatedWork W2312944328 @default.
• W4367396600 hasRelatedWork W2357245789 @default.
• W4367396600 hasRelatedWork W2363755036 @default.
• W4367396600 hasRelatedWork W2379088701 @default.
• W4367396600 hasRelatedWork W2581587783 @default.
• W4367396600 hasRelatedWork W2809928629 @default.
• W4367396600 hasRelatedWork W2892029697 @default.
• W4367396600 hasVolume "614" @default.
• W4367396600 isParatext "false" @default.
• W4367396600 isRetracted "false" @default.

• next